Home » Half-Reaction Method

Half-Reaction Method

1920

Complex redox reactions can be balanced using the half-reaction method. The overall reaction is split into two separate half-reactions: one for oxidation and one for reduction. Each half-reaction is balanced for atoms and charge independently, often by adding H+, OH-, and H2O in aqueous solutions. Finally, the electron counts are equalized and the half-reactions are combined.

The half-reaction method, also known as the ion-electron method, provides a systematic way to balance redox equations that would be difficult to balance by simple inspection. The process involves several steps. First, the reaction is split into an oxidation half-reaction and a reduction half-reaction. For each half-reaction, all elements other than oxygen and hydrogen are balanced. Then, oxygen atoms are balanced by adding water (\(H_2O\)) molecules. Hydrogen atoms are then balanced by adding hydrogen ions (\(H^+\)) in acidic solution, or water molecules in basic solution (with \(OH^-\) added to the other side).

After mass is balanced, charge is balanced by adding electrons (\(e^-\)) to the more positive side. The oxidation half-reaction will have electrons as a product, while the reduction half-reaction will have them as a reactant. The next crucial step is to multiply each half-reaction by an integer so that the number of electrons lost in the oxidation half equals the number of electrons gained in the reduction half. Finally, the two balanced half-reactions are added together, and any species that appear on both sides of the equation are canceled out. This rigorous method ensures that both mass and charge are conserved, which is essential for accurate stoichiometric analysis.

UNESCO Nomenclature: 2201
– Analytical chemistry

Type

Software/Algorithm

Disruption

Substantial

Usage

Widespread Use

Precursors

  • law of conservation of mass
  • law of conservation of charge
  • understanding of redox as electron transfer
  • concept of ions in solution

Applications

  • stoichiometric calculations in analytical chemistry
  • electrochemistry (describing processes at electrodes)
  • corrosion science
  • environmental chemistry (e.g., analyzing water treatment processes)

Patents:

NA

Potential Innovations Ideas

Professionals (100% free) Membership Required

You must be a Professionals (100% free) member to access this content.

Join Now

Already a member? Log in here
Related to: half-reaction, balancing equations, redox stoichiometry, electrochemistry, oxidation half-reaction, reduction half-reaction, ion-electron method, aqueous solution

Leave a Reply

Your email address will not be published. Required fields are marked *

AVAILABLE FOR NEW CHALLENGES
Mechanical Engineer, Project or R&D Manager
Effective product development

Available for a new challenge on short notice.
Contact me on LinkedIn
Plastic metal electronics integration, Design-to-cost, GMP, Ergonomics, Medium to high-volume devices & consumables, Regulated industries, CE & FDA, CAD, Solidworks, Lean Sigma Black Belt, medical ISO 13485

We are looking for a new sponsor

 

Your company or institution is into technique, science or research ?
> send us a message <

Receive all new articles
Free, no spam, email not distributed nor resold

or you can get your full membership -for free- to access all restricted content >here<

Historical Context

(if date is unknown or not relevant, e.g. "fluid mechanics", a rounded estimation of its notable emergence is provided)

Related Invention, Innovation & Technical Principles

Scroll to Top

You May Also Like