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范德华状态方程

1873
  • Johannes Diderik van der Waals
19th-century laboratory with Van der Waals equation and scientific instruments.

(图片仅供参考)

修正流体状态方程 理想气体定律 为了近似模拟真实气体的行为,它引入了两个参数:`a` 用于描述长程分子间吸引力(范德华力),`b` 用于描述…… 有限体积 被气体分子占据。方程为[latex](P + frac{an^2}{V^2})(V – nb) = nRT[/latex].

The Van der Waals equation of state was a groundbreaking development in thermodynamics, providing the first realistic description of real gases and their condensation into liquids. It starts with the ideal gas law, [latex]PV = nRT[/latex], and applies two crucial corrections. The first correction addresses the volume. In an ideal gas, particles are treated as points with no volume. The Van der Waals equation subtracts a term ‘nb’ from the container volume [latex]V[/latex], where ‘b’ is the volume excluded by a mole of particles. This term, [latex](V – nb)[/latex], represents the actual free volume available for the molecules to move in.

The second, more significant correction accounts for intermolecular attractive forces. These forces reduce the pressure exerted by the gas on the container walls because molecules near the wall are pulled inwards by their neighbors. This reduction in pressure is proportional to the square of the particle density ([latex]n/V[/latex]), leading to the correction term [latex]a(n/V)^2[/latex] which is added to the measured pressure [latex]P[/latex]. The parameter ‘a’ is a measure of the average attraction between particles. By incorporating these two parameters, the equation can successfully model the liquid-gas phase transition and predict the existence of a critical point, above which no distinct liquid and gas phases exist. It was for this work that van der Waals received the Nobel Prize in Physics in 1910.

UNESCO Nomenclature: 2212
– Thermodynamics

类型

Mathematical Model

中断

Foundational

用法

广泛使用

前体

  • 理想气体定律 (Boyle’s Law, Charles’s Law, Avogadro’s Law)
  • 克劳修斯和 Maxwell
  • 分子间力和有限原子尺寸的早期概念

应用程序

  • 真实气体的建模及其与理想行为的偏差
  • 液气相变和临界点的预测
  • 热力学 化学工程中的物性计算
  • 更复杂状态方程的基础模型

专利:

NA

潜在创新理念

  • 高压工业过程先进状态方程的开发
  • 人工智能驱动的新型化学混合物相行为预测
  • 使用非理想气体模型校准的实时气体泄漏检测系统
  • 结合真实气体效应的行星大气模拟器
  • 超临界流体萃取工艺的优化
  • 采用非理想流体的高效制冷循环设计
  • 深海天然气水合物形成模拟软件
  • 用于可视化理想气体行为偏差的教育工具
  • 用于校正工业管道流量计读数的算法
  • 气溶胶形成和扩散的预测模型
相关内容:范德瓦尔斯方程、真实气体、状态方程、分子间作用力、分子体积、临界点、热力学、相变、压力、体积。

历史背景

范德华状态方程

1865
1868
1870
1873
1877
1880
1882-01-01
1861
1865
1869
1871
1876
1877
1880
1882-01-01

(如果日期未知或不相关,例如“流体力学”,则提供其显著出现的近似估计)

第十年 周年纪念日

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