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薄膜堆積のためのスピンコーティング

1958
クリーンルーム内で薄膜成膜のためのスピンコーティングを行う実験室技術者。

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Spin coating is a procedure for depositing uniform thin films onto flat substrates. An excess of a coating solution is placed on the substrate, which is then rotated at high speed. 遠心力 溶液を塗布し、溶媒の蒸発または硬化によってフィルムが固化し、最終的な厚さは以下によって決定されます。 粘度集中力、そして回転速度。

The spin coating process is divided into four main stages: deposition, spin-up, spin-off, and evaporation. In the deposition stage, an excess of the coating fluid is dispensed onto the substrate’s surface. During the spin-up stage, the substrate is rapidly accelerated to its final, desired rotation speed, causing the fluid to flow radially outward due to 遠心力. The spin-off stage follows, where the excess fluid is ejected from the substrate’s edge, and the film thins. The final stage is evaporation, where the solvent evaporates from the film, leaving behind the solid coating. The thickness of the resulting film is highly dependent on several parameters. The key relationship was modeled by Emslie, Bonner, and Peck, showing that the final film thickness [latex]h_f[/latex] is proportional to the inverse square root of the angular velocity [latex]\omega[/latex], the initial solution concentration, and the solvent evaporation rate, and is also a function of the fluid 粘度 [latex]\nu[/latex]. The formula is often simplified as [latex]h_f \propto \omega^{-1/2}[/latex]. This technique is favored for its simplicity, speed, and ability to produce highly uniform films with thicknesses ranging from a few nanometers to several micrometers on a laboratory scale. However, it is inherently a batch process and can be wasteful, as a significant portion of the initial solution is flung off the substrate.

UNESCO Nomenclature: 3322
材料技術

タイプ

物理的プロセス

混乱

増分

使用法

広く普及している

前駆物質

  • クリスティアン・ホイヘンスによる遠心力の発見
  • 開発 電動モーター
  • 可溶性ポリマーおよびフォトレジストの合成
  • 流体力学と溶媒蒸発の原理に関する理解

アプリケーション

  • マイクロエレクトロニクスおよび半導体デバイスの製造
  • 反射防止層などの光学コーティングの製造
  • 有機発光ダイオード(OLED)の製造
  • コンパクトディスク(CD)およびデジタル多用途ディスク(DVD)の製造
  • 新規材料およびセンサーの研究開発

特許:

NA

潜在的なイノベーションのアイデア

  • automated multi-substrate spin coating systems for high-throughput research
  • in-situ monitoring of film thickness during spinning using optical interferometry
  • development of solvent-free or water-based solutions for eco-friendly spin coating
  • megasonic-assisted spin coating to reduce defects and improve uniformity
  • spin coating on flexible and non-planar substrates using specialized chucks
  • integration with inkjet printing for patterned multi-layer device fabrication
  • closed-chamber systems with controlled atmosphere and solvent 蒸気圧
  • development of “smart” photoresists that self-planarize during spinning
  • use of supercritical fluids as solvents for residue-free evaporation
  • portable, battery-operated spin coaters for field research and diagnostics
関連キーワード:スピンコーティング、薄膜、成膜、基板、遠心力、半導体、フォトリソグラフィー、ポリマー溶液、均一コーティング、材料科学。

歴史的背景

薄膜堆積のためのスピンコーティング

1950
1950
1955
1958
1960
1960
1960
1950
1950
1955
1956
1960
1960
1960
1960

(日付が不明または関連性がない場合、例えば「流体力学」などでは、その注目すべき出現時期の概算値が提示されます。)

10年目 周年

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