Home » Pitting Corrosion

Pitting Corrosion

1930

Pitting corrosion is a localized form of corrosion that leads to the creation of small holes, or ‘pits,’ in a metal. It is one of the most destructive forms because it is difficult to detect, predict, and design against. Pitting can cause catastrophic failure of a structure with only a small percentage of total mass loss.

Pitting is an autocatalytic process. It typically initiates at small surface defects, inclusions, or scratches, especially on passive metals like stainless steel or aluminum. The process begins with the local breakdown of the passive film, often triggered by aggressive anions, most notably chloride (\(Cl^-\)). Once the film is breached, an active corrosion cell is established. The small area of exposed metal becomes the anode, and the large surrounding passive surface becomes the cathode.

Inside the pit, metal dissolution occurs, for example \(Fe \\rightarrow Fe^{2+} + 2e^-\). The resulting positive metal ions attract negative chloride ions from the solution into the pit to maintain charge neutrality. This leads to the formation of metal chlorides, such as \(FeCl_2\), which then hydrolyze with water: \(FeCl_2 + 2H_2O \\rightarrow Fe(OH)_2 + 2HCl\). This reaction produces hydrochloric acid, which dramatically lowers the pH inside the pit, making the local environment highly acidic and aggressive. This increased acidity further accelerates metal dissolution and prevents the passive film from reforming, creating a self-sustaining cycle that causes the pit to grow deeper. The exterior surface remains protected, masking the severe damage occurring beneath.

UNESCO Nomenclature: 3314
– Materials science

Type

Chemical Process

Disruption

Substantial

Usage

Widespread Use

Precursors

  • Discovery and use of passive metals like stainless steel
  • Understanding of electrochemical cells and passivation
  • Increased use of materials in chloride-rich environments (e.g., marine, chemical industry)

Applications

  • failure analysis in chemical processing plants
  • inspection protocols for pipelines and storage tanks
  • materials selection for marine environments
  • design of medical implants to avoid in-vivo pitting

Patents:

NA

Potential Innovations Ideas

Professionals (100% free) Membership Required

You must be a Professionals (100% free) member to access this content.

Join Now

Already a member? Log in here
Related to: pitting corrosion, localized corrosion, passive film, chloride, stainless steel, autocatalytic, failure analysis, corrosion pit

Leave a Reply

Your email address will not be published. Required fields are marked *

AVAILABLE FOR NEW CHALLENGES
Mechanical Engineer, Project or R&D Manager
Effective product development

Available for a new challenge on short notice.
Contact me on LinkedIn
Plastic metal electronics integration, Design-to-cost, GMP, Ergonomics, Medium to high-volume devices & consumables, Regulated industries, CE & FDA, CAD, Solidworks, Lean Sigma Black Belt, medical ISO 13485

We are looking for a new sponsor

 

Your company or institution is into technique, science or research ?
> send us a message <

Receive all new articles
Free, no spam, email not distributed nor resold

or you can get your full membership -for free- to access all restricted content >here<

Historical Context

(if date is unknown or not relevant, e.g. "fluid mechanics", a rounded estimation of its notable emergence is provided)

Related Invention, Innovation & Technical Principles

Scroll to Top

You May Also Like