Thermoelectric Figure of Merit (ZT)

Plasticity is the theory describing the deformation of a solid material undergoing non-reversible changes of shape in response to applied forces. Unlike elasticity, where deformation is recovered upon unloading, plastic deformation is permanent. The theory involves a yield criterion to define the onset of plasticity, a flow rule to describe the evolution of plastic strain, and a hardening rule.

The bathtub curve is a graphical model illustrating three phases of a product's life in terms of failure rate. It starts with a high but decreasing 'infant mortality' rate, followed by a low, constant 'useful life' rate, and concludes with an increasing 'wear-out' rate. MTBF calculations using a constant failure rate (\(\lambda\)) are typically only valid during the central 'useful life' phase.

A solar cell can be modeled by an equivalent electrical circuit. The simplest model includes a current source representing the photogenerated current (\(I_L\)), in parallel with a diode representing the p-n junction. A more accurate model adds a parallel shunt resistance (\(R_{sh}\)) for leakage currents and a series resistance (\(R_s\)) for contact and bulk material resistance.

The Deborah number is a dimensionless quantity in rheology, used to characterize the fluidity of materials. It is the ratio of the relaxation time, which is an intrinsic property of the material, to the characteristic time scale of the experiment or observation. The formula is \(De = \frac{t_c}{t_p}\), where \(t_c\) is the relaxation time and \(t_p\) is the observation time.

Repeatability assesses precision under identical conditions, while reproducibility assesses precision when one or more conditions change, such as the operator, instrument, or location. Reproducibility variance is always greater than or equal to repeatability variance. This distinction is crucial for understanding measurement variability, especially in inter-laboratory comparisons where conditions are inherently different.

Cleanrooms utilize two primary airflow principles to control contamination. Turbulent (or non-unidirectional) flow involves mixed air streams, suitable for less stringent classes (ISO 6-9). Laminar (or unidirectional) flow uses parallel, constant-velocity air streams to sweep particles out of the environment, essential for high-purity applications like ISO 1-5, preventing cross-contamination and ensuring rapid particle removal.

The Weissenberg effect is a phenomenon in viscoelastic fluids where the fluid climbs up a rotating rod inserted into it. This is contrary to the behavior of Newtonian fluids, which are pushed outwards by centrifugal force, forming a vortex. The effect is caused by normal stress differences that develop in the fluid under shear.

A Pourbaix diagram, also known as a potential/pH diagram, is a thermodynamic chart that maps the stable equilibrium phases of an aqueous electrochemical system. It graphically shows the conditions of potential (\(E_H\)) and pH under which a metal is immune (thermodynamically stable), passivated (forms a stable protective film), or susceptible to corrosion (forms soluble ions).

Digital circuits are categorized into two main types: combinational and sequential logic. In combinational logic, the output is a pure function of the present input values only (e.g., an adder). In sequential logic, the output depends not only on the current inputs but also on the past sequence of inputs, as these circuits have memory elements (e.g., a flip-flop).

A thermal lance achieves temperatures of 3,500 °C to 4,500 °C, far exceeding conventional torches. This intense heat does not just melt the target material. The jet of pure oxygen also causes rapid oxidation of the material itself, effectively making it part of the fuel source. This combined melting and burning action allows it to cut through thick steel, concrete, and rock.

The fundamental building block of modern digital electronics is the transistor, specifically the MOSFET (Metal-Oxide-Semiconductor Field-Effect Transistor). It operates as an electronically controlled switch. By applying a voltage to its gate terminal, the flow of current between its source and drain terminals can be turned on (representing a '1') or off (representing a '0'), enabling the implementation of logic gates.

Mean Time Between Failures (MTBF) is a reliability metric representing the predicted elapsed time between inherent failures of a repairable system. For systems with a constant failure rate \(\lambda\), MTBF is its reciprocal: \(MTBF = 1/\lambda\). This simple relationship is fundamental in reliability engineering for predicting system uptime and planning maintenance schedules, assuming failures follow an exponential distribution.

For repairable systems, Mean Time Between Failures (MTBF) is the sum of Mean Time To Failure (MTTF) and Mean Time To Repair (MTTR). The formula is \(MTBF = MTTF + MTTR\). MTTF represents the average operational time before a failure, while MTTR is the average time taken to repair the system. This distinction is critical for understanding system availability.

For a system of components in series, where any single failure causes system failure, the overall failure rate is the sum of individual rates. The system's MTBF is the reciprocal of this sum: \(MTBF_{system} = (\sum_{i=1}^{n} \lambda_i)^{-1} = (1/MTBF_1 + 1/MTBF_2 + ... + 1/MTBF_n)^{-1}\). This implies the system's MTBF is always less than the lowest individual component's MTBF.