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Dernières publications et brevets sur les batteries sodium-ion

Batteries sodium-ion

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Batteries sodium-ion
La technologie des batteries sodium-ion offre une alternative prometteuse à l'utilisation de l'énergie solaire. lithium-ion avec des matériaux de cathode et d'anode uniques, en mettant l'accent sur le coût, la stabilité et la performance dans les applications de stockage d'énergie.

Les batteries sodium-ion sont des cellules de stockage d'énergie électrochimique qui remplacent les ions sodium par des ions sodium. lithium en tant qu'espèce porteuse de charge faisant la navette entre la cathode et l'anode pendant les cycles de charge et de décharge, fonctionnant selon une chimie d'insertion et d'extraction mécaniquement analogue à celle du lithium-ion, mais régie par le rayon ionique plus grand du sodium, son potentiel de réduction plus faible et son abondance crustale nettement plus importante.

La technologie des matériaux de cathode se divise en trois grandes familles :

  • oxydes de métaux de transition en couches
  • analogues du bleu de Prusse
  • composés polyanioniques, notamment les phosphates et les sulfates de type NASICON

Chacune présente des compromis distincts entre capacité spécifique, plateau de tension, stabilité structurelle sous sodiation répétée et coût de synthèse ; aucune chimie de cathode n'a atteint la consolidation du marché que détiennent NMC et LFP dans le lithium-ion.

Du côté de l'anode, la capacité négligeable d'intercalation du sodium du graphite le rend inadapté, ce qui oriente la recherche vers le carbone dur dérivé de la biomasse ou de précurseurs de résine comme norme pratique actuelle, les anodes en métal sodique représentant une frontière à plus haute énergie mais sujette à la dendrite. La formulation de l'électrolyte - sels NaPF6 ou NaClO4 dans des solvants éther ou carbonate, liquides ioniques ou conducteurs de sodium à l'état solide émergents - détermine de manière critique la chimie de l'interphase de l'électrolyte solide qui régit l'efficacité coulombienne du premier cycle, la capacité de débit et le vieillissement calendaire.

 

 Les publications et brevets indexés ci-dessous traitent de la synthèse des matériaux de cathode et d'anode, de l'ingénierie des électrolytes, de la caractérisation de l'interface électrolyte solide (SEI), de la conception du format de cellule, de l'optimisation du protocole de formation et de la modélisation technico-économique au niveau du système.

Voici notre dernière sélection de publications et brevets mondiaux en anglais sur les batteries sodium-ion, parmi de nombreuses revues scientifiques en ligne, classées et axées sur batterie sodium-ion, cellule Na-ion, cathode sodium-ion, cathode oxyde stratifié sodium, cathode analogue au bleu de Prusse, cathode polyanionique sodium, cathode NASICON, anode de carbone dur sodium, anode de carbone mou sodium, anode métallique sodium, électrolyte sodium-ion, électrolyte sodium à base d'éther, électrolyte de sel de sodium, électrolyte NaPF6, sodium-ion, électrolyte solide et couche SEI sodium-ion.

All-solid-state battery

Patent published on the 2026-05-28 in WO under Ref WO2026111067 by SAMSUNG ELECTRO MECH CO LTD [KR] (Kim Dongwon [kr], Kim Taehoon [kr], Keum Donghoon [kr], Kim Junhyeon [kr], Kim Han [kr])

Abstract: Provided is an all-solid-state battery including a positive electrode layer, a negative electrode layer, and a solid electrolyte layer disposed between the positive electrode layer and the negative electrode layer. The positive electrode layer includes a positive electrode active material comprising a core containing a lithium metal oxide and a surface layer formed on at least part of the core surface. The surface layer includes a first material containing at least one transition metal selected [...]


Our summary: The all-solid-state battery consists of a positive electrode layer, a negative electrode layer, and a solid electrolyte layer. The positive electrode includes a core of lithium metal oxide and a surface layer with transition metals. The surface layer also contains metals such as magnesium, aluminum, and titanium.

all-solid-state battery, solid electrolyte, positive electrode, lithium metal oxide

Patent

All-solid-state battery and method of manufacturing the same

Patent published on the 2026-05-28 in WO under Ref WO2026111063 by SAMSUNG ELECTRO MECH CO LTD [KR] (Kim Dongwon [kr], Kim Nahyeon [kr], Kim Namgyu [kr], Lee Wonyoung [kr], Kim Han [kr])

Abstract: The present disclosure relates to an all-solid-state battery and a method of manufacturing the same, including a positive electrode layer, a negative electrode layer, and a solid electrolyte layer stacked between the positive electrode layer and the negative electrode layer, wherein the positive electrode layer includes a positive electrode current collecting layer including a current collecting material and a first positive electrode active material; a first positive electrode active material l[...]


Our summary: The disclosure presents an all-solid-state battery design with a positive electrode layer, a negative electrode layer, and a solid electrolyte layer. It details the structure of the positive electrode layer, which includes a current collecting layer and two active material layers. The method of manufacturing the battery is also described.

all-solid-state battery, solid electrolyte, positive electrode, manufacturing method

Patent

All-solid-state rechargeable battery and method for manufacturing all-solid-state rechargeable battery

Patent published on the 2026-05-27 in EP under Ref EP4749695 by SAMSUNG SDI CO LTD [KR] (Kim Hyunwoo [kr])

Abstract: [0001] An all-solid rechargeable battery includes a first electrode powder layer, a solid electrolyte powder layer disposed on the first electrode powder layer, and a second electrode powder layer disposed on the solid electrolyte powder layer.[...]


Our summary: The all-solid-state rechargeable battery consists of a first electrode powder layer, a solid electrolyte powder layer, and a second electrode powder layer. The layers are arranged sequentially to form the battery structure. A method for manufacturing this type of battery is also described.

all-solid-state battery, solid electrolyte, electrode layers, manufacturing method

Patent

Electrolyte composition with improved high-temperature safety and lithium secondary battery comprising same

Patent published on the 2026-05-27 in EP under Ref EP4749747 by LG ENERGY SOLUTION LTD [KR] (Suh Soo Min [kr], Lee Chul Haeng [kr], Ahn Kyoung Ho [kr], Oh Young Ho [kr], Jeong You Kyeong [kr], Im Tae Yeong [kr])

Abstract: [0001] The present disclosure relates to an electrolyte composition for lithium secondary batteries. The electrolyte composition for lithium secondary batteries includes a fluorine-substituted linear ester solvent and a fluorine-substituted acrylic additive as a non-aqueous organic solvent and an electrolyte additive, respectively, thereby enabling uniform formation of a solid electrolyte interface layer (SEI layer) with high lithium ion conductivity and excellent heat resistance on the negative[...]


Our summary: The disclosure presents an electrolyte composition for lithium secondary batteries that enhances high-temperature safety. It includes a fluorine-substituted linear ester solvent and a fluorine-substituted acrylic additive. This composition improves lithium ion conductivity and reduces heat generation during battery activation.

Electrolyte composition, lithium secondary battery, solid electrolyte interface, high-temperature safety

Patent

Methods for improving critical current density in a sulfide-based all-solid-state lithium-ion battery

Patent published on the 2026-05-21 in WO under Ref WO2026106326 by UNIV CALIFORNIA [US] (Liu Ping [us], Zhou Ke [us], Liu Mengchen [us], Oh Jeongwoo [kr], Song Min Sang [kr])

Abstract: Solid electrolyte compositions and solid-state batteries are disclosed, which comprise a solid electrolyte layer including a sulfide-containing solid-state electrolyte material and a compound of Chemical Formula 1. The sulfide-containing solid-state electrolyte material includes but is not limited to Li6PS5Cl ("LPSC"), an LPS-based glass or glass ceramic of formula xLi2S·yP2S5, wherein x+y=1, or an argyrodite-based sulfide-based solid electrolyte or formula Li6PS5X, wherein X = Cl, Br, or I) or[...]


Our summary: This content discusses methods to enhance critical current density in sulfide-based all-solid-state lithium-ion batteries. It describes solid electrolyte compositions that include sulfide-containing materials like Li6PS5Cl and various formulations. The focus is on improving performance through advanced solid electrolyte layers.

sulfide electrolyte, solid-state battery, critical current density, lithium-ion battery

Patent

Heating element and solid state battery comprising the same, and methods of making and operating thereof

Patent published on the 2026-05-21 in US under Ref US20260142267 by AMPCERA INC [US] (Du Hui [us], Yi Eongyu [us], Brown James Emery [us])

Abstract: [0000] A solid-state battery comprising a positive electrode and a negative electrode, with a solid electrolyte layer positioned between them. The battery includes a positive current collector in electrical contact with the positive electrode and a negative current collector in electrical contact with the negative electrode. A heating element is situated in proximity to at least one of the current collectors, comprising a polymer substrate with a first surface and a second surface. A conductive [...]


Our summary: The solid-state battery features a positive and negative electrode separated by a solid electrolyte. A heating element is integrated near the current collectors, utilizing a polymer substrate with a conductive oxide layer. The design includes insulation to enable efficient heating for optimal battery operation.

solid-state battery, heating element, polymer substrate, conductive oxide

Patent

Crosslinked Zwitterionic PVA-g-SBMA/PEDOT:PSS Networks for Mechanically Robust All-Solid-State Electrolytes

Published on 2026-01-28 by Chia-Wen Wei, Chia-Yu Chen, Shyh-Chyang Luo, Dmitry G. Belov, Szu-Nan Yang @MDPI

Abstract: Conventional lithium-ion batteries face issues like electrolyte leakage and interface instability. Solid-state lithium batteries with solid electrolytes address these, while solid-state polymer electrolytes (SPEs) offer safety and flexibility. This study primarily aimed to develop and synthesize a graft copolymer, PVA-g-SBMA, which was successfully synthesized by grafting [2-(methacryloyloxy)ethyl] dimethyl-(3-sulfopropyl)ammonium hydroxide (SBMA) onto poly(vinyl alcohol) (PVA). PVA provided exc[...]


Our summary: This study developed a graft copolymer, PVA-g-SBMA, by grafting SBMA onto PVA to enhance ionic conductivity and mechanical properties in solid-state electrolytes. The copolymer was crosslinked with PEDOT:PSS to form a robust network, improving film performance. The optimal system achieved a conductivity of 4.9 × 10⁻⁴ S/cm at room temperature with specific lithium salt concentrations.

Crosslinked, Zwitterionic, Solid-state, Electrolytes

Publication

Advances in Sodium Ion Batteries Based on Mixed Electrolytes of ILs and Organic Solvents

Published on 2026-01-28 by Sajjad Ghiyami, Claudio Mele @MDPI

Abstract: Sodium-ion batteries (SIBs) represent a topic of extreme interest in the research field, especially because the materials used are cheaper than those in lithium-ion batteries (LIBs). In SIBs, the choice of cathodes and electrolytes is very important because they will affect the energy density, cycling stability, and safety of the battery. This work focuses on the prospect of hybrid electrolyte cells that incorporate ionic liquids (ILs) into organic liquids in order to improve the safety and perf[...]


Our summary: This study explores the use of hybrid electrolytes combining ionic liquids and organic solvents in sodium-ion batteries. It highlights improvements in ionic conductivity, electrochemical stability, and thermal safety. The research suggests that these advancements could enhance the performance and lifecycle of sodium-ion battery technology for large-scale energy storage applications.

Sodium-ion batteries, hybrid electrolytes, ionic liquids, energy storage

Publication

Sujets abordés : Batteries sodium-ion, stockage électrochimique de l'énergie, matériaux de cathode, matériaux d'anode, oxydes de métaux de transition en couches, analogues du bleu de Prusse, composés polyanioniques, intercalation du sodium, interphase de l'électrolyte solide, efficacité coulombienne, formulation de l'électrolyte, modélisation technico-économique, ISO 18604, IEC 62619, IEC 62133, ASTM D7862, et ISO 9001.

Glossaire des termes utilisés

Network-attached storage (NAS): Un périphérique de stockage connecté à un réseau permet l'accès et le partage de données entre plusieurs utilisateurs et appareils, offrant généralement des fonctions centralisées de stockage, de sauvegarde et de gestion de fichiers. Il fonctionne indépendamment d'un ordinateur et est accessible via des protocoles réseau standard.

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