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Últimas publicaciones y patentes sobre baterías de iones de sodio

Baterías de iones de sodio

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Baterías de iones de sodio
La tecnología de las baterías de iones de sodio ofrece una alternativa prometedora a la ión-litio con materiales únicos de cátodo y ánodo, haciendo hincapié en el coste, la estabilidad y el rendimiento en aplicaciones de almacenamiento de energía.

Las pilas de iones de sodio son acumuladores electroquímicos de energía que sustituyen los iones de sodio por litio como la especie portadora de carga que se desplaza entre el cátodo y el ánodo durante los ciclos de carga y descarga, operando con una química de inserción y extracción mecánicamente análoga a la del ión-litio, pero regida por el mayor radio iónico del sodio, su menor potencial de reducción y su abundancia sustancialmente mayor en la corteza terrestre.

La tecnología de materiales catódicos se divide en tres familias principales:

  • óxidos de metales de transición en capas
  • Análogos del azul de Prusia
  • compuestos polianiónicos, incluidos fosfatos y sulfatos de tipo NASICON.

Cada una presenta ventajas e inconvenientes distintos en cuanto a capacidad específica, meseta de voltaje, estabilidad estructural bajo sodiación repetida y coste de síntesis; ninguna química de cátodo individual ha logrado la consolidación de mercado que tienen NMC y LFP en el sector de los iones de litio.

En cuanto a los ánodos, la capacidad insignificante de intercalación de sodio del grafito lo hace inadecuado, lo que dirige la investigación hacia el carbono duro derivado de la biomasa o de precursores de resina como norma práctica actual, mientras que los ánodos metálicos de sodio representan una frontera de mayor energía pero propensa a la dendrita. La formulación del electrolito (sales NaPF6 o NaClO4 en disolventes de éter o carbonato, líquidos iónicos o conductores de sodio en estado sólido emergentes) determina de forma crítica la química de la interfase del electrolito sólido que rige la eficiencia coulómbica del primer ciclo, la capacidad de velocidad y el envejecimiento del calendario.

 

 Las publicaciones y patentes que se indexan a continuación abordan la síntesis de materiales para cátodos y ánodos, la ingeniería de electrolitos, la caracterización de la capa SEI, el diseño del formato de celda, la optimización del protocolo de formación y la modelización tecnoeconómica a nivel de sistema.

Esta es nuestra última selección de publicaciones y patentes mundiales en inglés sobre Baterías de iones de sodio, entre muchas revistas científicas en línea, clasificadas y centradas en batería de iones de sodio, célula de Na-ion, cátodo de iones de sodio, cátodo de óxido estratificado de sodio, cátodo análogo al azul de Prusia, cátodo polianiónico de sodio, cátodo NASICON, ánodo de carbono duro de sodio, ánodo de carbono blando de sodio, ánodo metálico de sodio, electrolito de iones de sodio, electrolito a base de éter de sodio, electrolito de sal de sodio, electrolito NaPF6, iones de sodio, electrolito sólido y capa SEI de iones de sodio.

Llzo solid electrolyte doped with single element, method for preparing same, and all-solid-state lithium secondary battery including same

Patent published on the 2026-05-21 in WO under Ref WO2026106422 by TDL CO LTD [KR] (Kim Yoo Shin [kr], Kang Sung Won [kr], Kim Da Hye [kr], Lee Sang Hyun [kr], Choi Hui Sang [kr], Oh Hae Bin [kr], Yang Jin Geon [kr], Lee Seung Heon [kr])

Abstract: Disclosed is a method for preparing a solid electrolyte that has a cubic crystal structure with high structural stability by doping the Zr sites of LLZO with a single element (Sb, In, or Cd) in order to solve the problems of structural instability and low ionic conductivity when preparing LLZO by co-precipitation, wherein the method can improve ionic conductivity by increasing lithium ion transport pathways.[...]


Our summary: A method for preparing a solid electrolyte with a cubic structure is disclosed. The electrolyte is doped with a single element to enhance stability and conductivity. This approach improves lithium ion transport pathways in all-solid-state lithium batteries.

LLZO, solid electrolyte, ionic conductivity, doping

Patent

Methods for improving critical current density in a sulfide-based all-solid-state lithium-ion battery

Patent published on the 2026-05-21 in WO under Ref WO2026106326 by UNIV CALIFORNIA [US] (Liu Ping [us], Zhou Ke [us], Liu Mengchen [us], Oh Jeongwoo [kr], Song Min Sang [kr])

Abstract: Solid electrolyte compositions and solid-state batteries are disclosed, which comprise a solid electrolyte layer including a sulfide-containing solid-state electrolyte material and a compound of Chemical Formula 1. The sulfide-containing solid-state electrolyte material includes but is not limited to Li6PS5Cl ("LPSC"), an LPS-based glass or glass ceramic of formula xLi2S·yP2S5, wherein x+y=1, or an argyrodite-based sulfide-based solid electrolyte or formula Li6PS5X, wherein X = Cl, Br, or I) or[...]


Our summary: This content discusses methods to enhance critical current density in sulfide-based all-solid-state lithium-ion batteries. It describes solid electrolyte compositions that include sulfide-containing materials like Li6PS5Cl and various formulations. The focus is on improving performance through advanced solid electrolyte layers.

sulfide electrolyte, solid-state battery, critical current density, lithium-ion battery

Patent

Heating element and solid state battery comprising the same, and methods of making and operating thereof

Patent published on the 2026-05-21 in US under Ref US20260142267 by AMPCERA INC [US] (Du Hui [us], Yi Eongyu [us], Brown James Emery [us])

Abstract: [0000] A solid-state battery comprising a positive electrode and a negative electrode, with a solid electrolyte layer positioned between them. The battery includes a positive current collector in electrical contact with the positive electrode and a negative current collector in electrical contact with the negative electrode. A heating element is situated in proximity to at least one of the current collectors, comprising a polymer substrate with a first surface and a second surface. A conductive [...]


Our summary: The solid-state battery features a positive and negative electrode separated by a solid electrolyte. A heating element is integrated near the current collectors, utilizing a polymer substrate with a conductive oxide layer. The design includes insulation to enable efficient heating for optimal battery operation.

solid-state battery, heating element, polymer substrate, conductive oxide

Patent

Lithium secondary battery

Patent published on the 2026-05-20 in EP under Ref EP4746065 by SK INNOVATION CO LTD [KR] (Park Seong Jin [kr], Park Doe Hee [kr], Park Myung Soo [kr], Lee Han Sol [kr], Choi Jae Young [kr])

Abstract: [0001] A lithium secondary battery according to embodiments of the present disclosure includes an anode, a cathode disposed opposite the anode, and an electrolyte. The anode includes a lithium metal layer and a solid electrolyte interphase (SEI) layer disposed on the lithium metal layer. The anode has a first peak ratio of 1 to 7.[...]


Our summary: A lithium secondary battery features an anode with a lithium metal layer and a solid electrolyte interphase. The cathode is positioned opposite the anode. The anode s first peak ratio is between 1 and 7.

lithium secondary battery, anode, cathode, solid electrolyte interphase

Patent

Method for producing sulfide solid electrolyte and method for producing all-solid-state cell

Patent published on the 2026-05-14 in AU under Ref AU2024372065 by MITSUBISHI GAS CHEMICAL COMPANY INC (Konya Masashi, Yoshida Yuto)

Abstract: Provided is a method for producing a sulfide solid electrolyte having high water resistance. The method for producing a sulfide solid electrolyte includes a step in which a sulfide solid electrolyte is subjected in a solvent to at least one treatment selected from the group consisting of a mixing treatment and a disaggregation treatment, wherein the solvent includes a solvent which is aprotic and contains an oxygen atom.[...]


Our summary: The method produces a sulfide solid electrolyte with high water resistance. It involves treating the electrolyte in an aprotic solvent. Treatments include mixing and disaggregation processes.

sulfide solid electrolyte, all-solid-state cell, water resistance, aprotic solvent

Patent

Membrane electrode assembly for water electrolysis and method for manufacturing the same

Patent published on the 2026-05-07 in US under Ref US20260125805 by TOYOTA MOTOR CO LTD [JP] (Kodama Tomoki [jp], Akita Yasuhiro [jp])

Abstract: A membrane electrode assembly for water electrolysis includes a solid electrolyte membrane, and an anode catalyst layer and a cathode catalyst layer that sandwich the solid electrolyte membrane. The solid electrolyte membrane includes a solid electrolyte layer, and a functional layer provided on an anode-side surface of the solid electrolyte layer. The anode catalyst layer is provided on a surface of the solid electrolyte membrane near the functional layer. The cathode catalyst layer is provided[...]


Our summary: The membrane electrode assembly consists of a solid electrolyte membrane sandwiched between anode and cathode catalyst layers. The solid electrolyte membrane features a functional layer on the anode side. This functional layer contains resin and dispersed catalytic metal particles.

membrane electrode assembly, water electrolysis, solid electrolyte membrane, catalyst layers

Patent

Crosslinked Zwitterionic PVA-g-SBMA/PEDOT:PSS Networks for Mechanically Robust All-Solid-State Electrolytes

Published on 2026-01-28 by Chia-Wen Wei, Chia-Yu Chen, Shyh-Chyang Luo, Dmitry G. Belov, Szu-Nan Yang @MDPI

Abstract: Conventional lithium-ion batteries face issues like electrolyte leakage and interface instability. Solid-state lithium batteries with solid electrolytes address these, while solid-state polymer electrolytes (SPEs) offer safety and flexibility. This study primarily aimed to develop and synthesize a graft copolymer, PVA-g-SBMA, which was successfully synthesized by grafting [2-(methacryloyloxy)ethyl] dimethyl-(3-sulfopropyl)ammonium hydroxide (SBMA) onto poly(vinyl alcohol) (PVA). PVA provided exc[...]


Our summary: This study developed a graft copolymer, PVA-g-SBMA, by grafting SBMA onto PVA to enhance ionic conductivity and mechanical properties in solid-state electrolytes. The copolymer was crosslinked with PEDOT:PSS to form a robust network, improving film performance. The optimal system achieved a conductivity of 4.9 × 10⁻⁴ S/cm at room temperature with specific lithium salt concentrations.

Crosslinked, Zwitterionic, Solid-state, Electrolytes

Publication

Advances in Sodium Ion Batteries Based on Mixed Electrolytes of ILs and Organic Solvents

Published on 2026-01-28 by Sajjad Ghiyami, Claudio Mele @MDPI

Abstract: Sodium-ion batteries (SIBs) represent a topic of extreme interest in the research field, especially because the materials used are cheaper than those in lithium-ion batteries (LIBs). In SIBs, the choice of cathodes and electrolytes is very important because they will affect the energy density, cycling stability, and safety of the battery. This work focuses on the prospect of hybrid electrolyte cells that incorporate ionic liquids (ILs) into organic liquids in order to improve the safety and perf[...]


Our summary: This study explores the use of hybrid electrolytes combining ionic liquids and organic solvents in sodium-ion batteries. It highlights improvements in ionic conductivity, electrochemical stability, and thermal safety. The research suggests that these advancements could enhance the performance and lifecycle of sodium-ion battery technology for large-scale energy storage applications.

Sodium-ion batteries, hybrid electrolytes, ionic liquids, energy storage

Publication

Temas tratados: Baterías de iones de sodio, almacenamiento electroquímico de energía, materiales catódicos, materiales anódicos, óxidos de metales de transición estratificados, análogos del azul de Prusia, compuestos polianiónicos, intercalación de sodio, interfase de electrolitos sólidos, eficiencia coulómbica, formulación de electrolitos, modelización tecnoeconómica, ISO 18604, IEC 62619, IEC 62133, ASTM D7862, e ISO 9001.

Glosario de términos utilizados

Network-attached storage (NAS): Dispositivo de almacenamiento conectado a una red que permite el acceso y el intercambio de datos entre múltiples usuarios y dispositivos, y que generalmente proporciona capacidades centralizadas de almacenamiento, copia de seguridad y gestión de archivos. Funciona de forma independiente de una computadora y se puede acceder a él mediante protocolos de red estándar.

Contexto histórico

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