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Últimas publicaciones y patentes sobre baterías de iones de sodio

Baterías de iones de sodio

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Baterías de iones de sodio
La tecnología de las baterías de iones de sodio ofrece una alternativa prometedora a la iones de litio con materiales únicos de cátodo y ánodo, haciendo hincapié en el coste, la estabilidad y el rendimiento en aplicaciones de almacenamiento de energía.

Las pilas de iones de sodio son acumuladores electroquímicos de energía que sustituyen los iones de sodio por litio como la especie portadora de carga que se desplaza entre el cátodo y el ánodo durante los ciclos de carga y descarga, operando con una química de inserción y extracción mecánicamente análoga a la del ión-litio, pero regida por el mayor radio iónico del sodio, su menor potencial de reducción y su abundancia sustancialmente mayor en la corteza terrestre.

La tecnología de materiales catódicos se divide en tres familias principales:

  • óxidos de metales de transición en capas
  • Análogos del azul de Prusia
  • compuestos polianiónicos, incluidos fosfatos y sulfatos de tipo NASICON.

Cada una presenta ventajas e inconvenientes distintos en cuanto a capacidad específica, meseta de voltaje, estabilidad estructural bajo sodiación repetida y coste de síntesis; ninguna química de cátodo individual ha logrado la consolidación de mercado que tienen NMC y LFP en el sector de los iones de litio.

En cuanto a los ánodos, la capacidad insignificante de intercalación de sodio del grafito lo hace inadecuado, lo que dirige la investigación hacia el carbono duro derivado de la biomasa o de precursores de resina como norma práctica actual, mientras que los ánodos metálicos de sodio representan una frontera de mayor energía pero propensa a la dendrita. La formulación del electrolito (sales NaPF6 o NaClO4 en disolventes de éter o carbonato, líquidos iónicos o conductores de sodio en estado sólido emergentes) determina de forma crítica la química de la interfase del electrolito sólido que rige la eficiencia coulómbica del primer ciclo, la capacidad de velocidad y el envejecimiento del calendario.

 

 Las publicaciones y patentes que se indexan a continuación abordan la síntesis de materiales para cátodos y ánodos, la ingeniería de electrolitos, la caracterización de la capa SEI, el diseño del formato de celda, la optimización del protocolo de formación y la modelización tecnoeconómica a nivel de sistema.

Esta es nuestra última selección de publicaciones y patentes mundiales en inglés sobre Baterías de iones de sodio, entre muchas revistas científicas en línea, clasificadas y centradas en batería de iones de sodio, célula de Na-ion, cátodo de iones de sodio, cátodo de óxido estratificado de sodio, cátodo análogo al azul de Prusia, cátodo polianiónico de sodio, cátodo NASICON, ánodo de carbono duro de sodio, ánodo de carbono blando de sodio, ánodo metálico de sodio, electrolito de iones de sodio, electrolito a base de éter de sodio, electrolito de sal de sodio, electrolito NaPF6, iones de sodio, electrolito sólido y capa SEI de iones de sodio.

Method for manufacturing anode active material layer and method for manufacturing secondary battery

Patent published on the 2026-06-11 in US under Ref US20260162953 by TOYOTA JIDOSHA KK [JP] (Imano Manabu [jp])

Abstract: A method for manufacturing an anode active material layer includes: a step of preparing an anode slurry by mixing an anode active material, a solid electrolyte, a conductive additive, a binder, and a solvent; a step of obtaining a parameter of the anode slurry using a dynamic viscoelasticity measuring device; a step of determining quality of a coating film based on the obtained parameter; and a step of applying the anode slurry that has been determined to be acceptable in the step of determining[...]


Our summary: The method involves preparing an anode slurry with specific components. It uses a dynamic viscoelasticity measuring device to obtain parameters of the slurry. The quality of the coating film is determined before applying the acceptable anode slurry.

anode active material, secondary battery, dynamic viscoelasticity, coating film quality

Patent

Negative electrode for all-solid-state sodium ion secondary battery, method for manufacturing same, and all-solid-state sodium ion secondary battery

Patent published on the 2026-06-11 in WO under Ref WO2026121155 by NIPPON ELECTRIC GLASS CO LTD [JP] (Tatsuoka Deguchi Mina [jp], Tsunoda Kei [jp], Demizu Masashi [jp], Yamauchi Hideo [jp])

Abstract: Provided are: a negative electrode for an all-solid-state sodium ion secondary battery, the negative electrode being capable of improving the initial charge/discharge efficiency, the conservation characteristics, the output characteristics, and the cycle characteristics of the all-solid-state sodium ion secondary battery; a method for manufacturing the negative electrode; and an all-solid-state sodium ion secondary battery. The negative electrode for an all-solid-state sodium ion secondary batte[...]


Our summary: This content describes a negative electrode designed for all-solid-state sodium ion secondary batteries. It highlights improvements in charge/discharge efficiency and cycle characteristics. Additionally, it outlines a manufacturing method for the negative electrode.

negative electrode, all-solid-state battery, sodium ion, manufacturing method

Patent

Solid electrolyte, method for producing same, and power storage device

Patent published on the 2026-06-11 in WO under Ref WO2026121260 by TOAGOSEI CO LTD [JP] (Hiraoka Hideki [jp], Goto Takeshi [jp])

Abstract: This solid electrolyte includes: a film-like porous body having communication holes; and molecular crystals containing, as structural units, an alkali metal salt and organic molecules having at least one type of atom selected from the group consisting of sulfur atoms, oxygen atoms, nitrogen atoms, and phosphorus atoms. The molecular crystals are retained in the communication holes.[...]


Our summary: The solid electrolyte features a porous film-like body with communication holes. It incorporates molecular crystals made from alkali metal salts and organic molecules containing specific atoms. These molecular crystals are securely held within the communication holes.

solid electrolyte, power storage device, alkali metal salt, molecular crystals

Patent

Method for manufacturing cathode active material layer and method for manufacturing secondary battery

Patent published on the 2026-06-11 in US under Ref US20260160658 by TOYOTA JIDOSHA KK [JP] (Imano Manabu [jp])

Abstract: [0000] A method for manufacturing a cathode active material layer includes: a step of preparing a cathode slurry by mixing a cathode active material, a solid electrolyte, a conductive additive, a binder, and a solvent; a step of obtaining a parameter of the cathode slurry using a dynamic viscoelasticity measuring device; a step of determining the quality of a coating film based on the parameter; and a step of applying the cathode slurry that has been determined to be acceptable in the step of de[...]


Our summary: The method involves preparing a cathode slurry with specific components. It measures the slurry s parameters using dynamic viscoelasticity. The quality of the coating film is determined before applying the acceptable slurry.

cathode active material, secondary battery, dynamic viscoelasticity, coating film quality

Patent

Solid electrolyte separator and all-solid-state battery comprising same

Patent published on the 2026-06-04 in WO under Ref WO2026116626 by SAMSUNG SDI CO LTD [KR] (Son Inhyuk [kr], Jo Sungnim [kr], Shim Kyueun [kr], Yun Jonghyuk [kr], Lim Hyungsub [kr], Park Taehyun [kr], Lee Jieun [kr])

Abstract: Provided are a solid electrolyte separator and an all-solid-state battery comprising same, the solid electrolyte separator: comprising a solid electrolyte and an ion-conductive polymer; and having an embossed portion formed on at least one surface thereof.[...]


Our summary: The content describes a solid electrolyte separator used in all-solid-state batteries. This separator consists of a solid electrolyte combined with an ion-conductive polymer. It features an embossed portion on at least one of its surfaces.

solid electrolyte, all-solid-state battery, ion-conductive polymer, embossed separator

Patent

All-solid-state battery

Patent published on the 2026-06-04 in WO under Ref WO2026116617 by SAMSUNG ELECTRO MECH CO LTD [KR] (Kim Junhyeon [kr], Jung Jihyung [kr], Lee Tae Gyeom [kr], Kim Nahyeon [kr], Kim Han [kr], Kim Doyeon [kr])

Abstract: Provided are an all-solid-state battery and a method of manufacturing the same. The all-solid-state battery includes a positive electrode layer, a negative electrode layer, and a solid electrolyte layer between the positive electrode layer and the negative electrode layer The solid electrolyte layer includes a first material and a second material The first material includes at least one selected from a lithium chloroboracite (LCBA)-based compound and a lithium borosilicate (LBSO)-based compound,[...]


Our summary: The all-solid-state battery consists of a positive electrode, a negative electrode, and a solid electrolyte layer. The solid electrolyte layer is made from a combination of lithium-based compounds and selected metals. A method for manufacturing this battery is also provided.

all-solid-state battery, solid electrolyte, lithium compounds, manufacturing method

Patent

Crosslinked Zwitterionic PVA-g-SBMA/PEDOT:PSS Networks for Mechanically Robust All-Solid-State Electrolytes

Published on 2026-01-28 by Chia-Wen Wei, Chia-Yu Chen, Shyh-Chyang Luo, Dmitry G. Belov, Szu-Nan Yang @MDPI

Abstract: Conventional lithium-ion batteries face issues like electrolyte leakage and interface instability. Solid-state lithium batteries with solid electrolytes address these, while solid-state polymer electrolytes (SPEs) offer safety and flexibility. This study primarily aimed to develop and synthesize a graft copolymer, PVA-g-SBMA, which was successfully synthesized by grafting [2-(methacryloyloxy)ethyl] dimethyl-(3-sulfopropyl)ammonium hydroxide (SBMA) onto poly(vinyl alcohol) (PVA). PVA provided exc[...]


Our summary: This study developed a graft copolymer, PVA-g-SBMA, by grafting SBMA onto PVA to enhance ionic conductivity and mechanical properties in solid-state electrolytes. The copolymer was crosslinked with PEDOT:PSS to form a robust network, improving film performance. The optimal system achieved a conductivity of 4.9 × 10⁻⁴ S/cm at room temperature with specific lithium salt concentrations.

Crosslinked, Zwitterionic, Solid-state, Electrolytes

Publication

Advances in Sodium Ion Batteries Based on Mixed Electrolytes of ILs and Organic Solvents

Published on 2026-01-28 by Sajjad Ghiyami, Claudio Mele @MDPI

Abstract: Sodium-ion batteries (SIBs) represent a topic of extreme interest in the research field, especially because the materials used are cheaper than those in lithium-ion batteries (LIBs). In SIBs, the choice of cathodes and electrolytes is very important because they will affect the energy density, cycling stability, and safety of the battery. This work focuses on the prospect of hybrid electrolyte cells that incorporate ionic liquids (ILs) into organic liquids in order to improve the safety and perf[...]


Our summary: This study explores the use of hybrid electrolytes combining ionic liquids and organic solvents in sodium-ion batteries. It highlights improvements in ionic conductivity, electrochemical stability, and thermal safety. The research suggests that these advancements could enhance the performance and lifecycle of sodium-ion battery technology for large-scale energy storage applications.

Sodium-ion batteries, hybrid electrolytes, ionic liquids, energy storage

Publication

Temas tratados: Baterías de iones de sodio, almacenamiento electroquímico de energía, materiales catódicos, materiales anódicos, óxidos de metales de transición estratificados, análogos del azul de Prusia, compuestos polianiónicos, intercalación de sodio, interfase de electrolitos sólidos, eficiencia coulómbica, formulación de electrolitos, modelización tecnoeconómica, ISO 18604, IEC 62619, IEC 62133, ASTM D7862, e ISO 9001.

Glosario de términos utilizados

Network-attached storage (NAS): Dispositivo de almacenamiento conectado a una red que permite el acceso y el intercambio de datos entre múltiples usuarios y dispositivos, y que generalmente proporciona capacidades centralizadas de almacenamiento, copia de seguridad y gestión de archivos. Funciona de forma independiente de una computadora y se puede acceder a él mediante protocolos de red estándar.

Contexto histórico

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(Si la fecha es desconocida o no es relevante, por ejemplo "mecánica de fluidos", se proporciona una estimación redondeada de su aparición notable)

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