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水成膜泡沫(AFFF)

1960
消防员在进行B类火灾扑救训练时使用水性成膜泡沫。

(图片仅供参考)

水成膜泡沫 (AFFF) 是一种高效的 B 类火灾(易燃液体)灭火剂。其功效源于 PFAS 基氟表面活性剂,它能显著降低水的表面张力。这使得泡沫能够迅速扩散到燃烧液体的表面,形成一道蒸汽屏障,抑制火焰燃烧并冷却燃料。

AFFF was a revolutionary development in firefighting technology. Before AFFF, protein-based foams were used, but they were less effective and slower to control large liquid fuel fires. The key innovation in AFFF is the use of fluorosurfactants. These molecules have a water-soluble (hydrophilic) head and a water-insoluble (hydrophobic) fluorocarbon tail. When mixed with water and aerated, they create a foam blanket. Crucially, as the foam drains, the fluorosurfactants create a thin aqueous 电影 that floats on the surface of the hydrocarbon fuel. This film has a surface tension lower than that of the fuel, allowing it to spread rapidly and reseal if disturbed. The film serves multiple purposes: it suppresses the release of flammable vapors, separates the fuel from oxygen, and the water content provides a cooling effect. This combination makes AFFF exceptionally fast and effective at extinguishing difficult-to-control liquid fires, which is why it became the standard for high-risk environments like airports and military installations. However, the environmental persistence and toxicity of the PFAS used in AFFF have led to it becoming a major source of groundwater contamination at training sites.

UNESCO Nomenclature: 3309
- 环境工程

类型

化工产品

中断

革命

用法

广泛使用

前体

  • 20 世纪初发明的蛋白质基灭火泡沫
  • 20 世纪 50 年代 3M 公司合成氟表面活性剂
  • 了解表面张力和成膜现象
  • 军队需要改进喷气燃料火灾的灭火措施

应用程序

  • 军事基地和机场
  • 民用机场
  • 炼油厂和石化厂
  • 消防部门应对燃油泄漏和火灾

专利:

NA

潜在创新理念

  • 采用新型碳氢化合物表面活性剂和聚合物的无氟灭火泡沫(f3)
  • 用于消防训练场的空气污染与水污染防治系统
  • 具有工程断裂点的可生物降解水泡沫配方
  • 超声波 foam generation systems that require less concentrate
  • 机器人灭火系统可以更精确地喷洒泡沫,以最大限度地减少环境排放
  • 使用生物累积潜力较低的短链全氟辛烷磺酸 (pfa) 的水和泡沫 (afff) 配方(目前也正在逐步淘汰)
  • 封装的 afff 剂,仅在高温下释放
  • 数字孪生 models of fire scenarios to optimize foam application strategies
  • 便携式电化学系统可现场销毁水污染水中的 PFA
  • 源自微生物的生物表面活性剂泡沫作为绿色替代品
相关术语:AFF、消防泡沫、氟表面活性剂、PFAS、B类火灾、易燃液体、表面张力、蒸汽屏障、环境污染、灭火。

历史背景

水成膜泡沫(AFFF)

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1962-10-09
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(如果日期未知或不相关,例如“流体力学”,则提供其显著出现的近似估计)

第十年 周年纪念日

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