Time-Dependent Viscosity: Thixotropy and Rheopexy

General relativity predicts that a massive, rotating object should 'drag' the fabric of spacetime around with it, a phenomenon known as frame-dragging or the Lense-Thirring effect. This means a gyroscope orbiting the rotating body will precess, not because of any applied torque, but because spacetime itself is being twisted by the body's rotation.

A Bingham plastic is a viscoplastic material that behaves as a rigid body at low stresses but flows as a viscous fluid at high stress. It is characterized by a yield stress, \(\tau_0\), which is the minimum shear stress required to initiate flow. Below this threshold, it does not deform. Common examples include toothpaste, mayonnaise, and clay slurries.

Shear-thinning, or pseudoplasticity, is a non-Newtonian behavior where a fluid's viscosity decreases with an increasing rate of shear stress. Many common substances, like ketchup or paint, exhibit this property. At rest, they are thick, but they flow more easily when shaken, stirred, or spread. This is often modeled by the Ostwald–de Waele power-law relationship.

Thixotropy and rheopexy describe time-dependent changes in viscosity. A thixotropic fluid's viscosity decreases over time under constant shear stress (e.g., yogurt becomes runnier when stirred). A rheopectic (or anti-thixotropic) fluid's viscosity increases over time under constant shear (e.g., some lubricants). These effects are reversible; the fluid returns to its original state after a period of rest.

A non-Newtonian fluid is one whose viscosity changes under an applied shear stress. Unlike a Newtonian fluid where viscosity is constant, its flow properties are not described by a linear relationship between shear stress (\(\tau\)) and shear rate (\(\dot{gamma}\)). This dependency can manifest as shear-thinning (viscosity decreases with stress) or shear-thickening (viscosity increases with stress).

The Weissenberg effect is a phenomenon in viscoelastic fluids where the fluid climbs up a rotating rod inserted into it. This is contrary to the behavior of Newtonian fluids, which are pushed outwards by centrifugal force, forming a vortex. The effect is caused by normal stress differences that develop in the fluid under shear.

The Deborah number is a dimensionless quantity in rheology, used to characterize the fluidity of materials. It is the ratio of the relaxation time, which is an intrinsic property of the material, to the characteristic time scale of the experiment or observation. The formula is \(De = \frac{t_c}{t_p}\), where \(t_c\) is the relaxation time and \(t_p\) is the observation time.

A black hole is a region of spacetime where gravity is so strong that nothing—no particles or even light—can escape. The boundary of this region is called the event horizon. Predicted by general relativity as a solution to the field equations, a black hole is the result of the complete gravitational collapse of a massive star.

General relativity predicts that the path of light is bent by gravity. When light from a distant source passes a massive object like a galaxy or a star, its path is deflected. This phenomenon, known as gravitational lensing, can magnify, distort, or create multiple images of the background source, acting like a cosmic telescope for observing the distant universe.

All quantum entities, such as photons and electrons, exhibit both particle and wave properties. Depending on the experimental setup, they can behave like a localized particle or a distributed wave. The de Broglie hypothesis states that any particle with momentum \(p\) has an associated wavelength \(\lambda = h/p\), where \(h\) is Planck's constant.

This is a fundamental equation in quantum mechanics that describes how the quantum state of a physical system changes over time. It is a linear partial differential equation for the wavefunction, \(\Psi(x, t)\). The time-dependent version is \(i\hbar\frac{\partial}{\partial t}\Psi = \hat{H}\Psi\), where \(\hat{H}\) is the Hamiltonian operator, representing the total energy of the system.

The Courant–Friedrichs–Lewy (CFL) condition is a necessary stability criterion for numerical solutions of hyperbolic partial differential equations using explicit time-integration schemes. It dictates that the time step size must be small enough that information does not travel further than one spatial grid cell per time step. For a 1D case, \(C = u \frac{\Delta t}{\Delta x} \le C_{max}\), ensuring numerical stability.

The Finite Element Method (FEM) is a powerful numerical technique for solving complex engineering and physics problems described by partial differential equations. It works by discretizing a continuous domain into a set of smaller, simpler subdomains called 'finite elements'. This allows for the approximate numerical solution of problems in structural analysis, heat transfer, fluid flow, and electromagnetism.

Plasticity is the theory describing the deformation of a solid material undergoing non-reversible changes of shape in response to applied forces. Unlike elasticity, where deformation is recovered upon unloading, plastic deformation is permanent. The theory involves a yield criterion to define the onset of plasticity, a flow rule to describe the evolution of plastic strain, and a hardening rule.

Molecular electronics explores using individual molecules or nanoscale molecular collections as fundamental electronic components. This approach aims to build circuits at the ultimate limit of miniaturization, far beyond traditional silicon-based technology. Key components include molecular wires, switches, and rectifiers, leveraging quantum mechanical properties like electron tunneling through molecular orbitals for their function.