A non-Newtonian fluid is one whose viscosity changes under an applied shear stress. Unlike a Newtonian fluid where viscosity is constant, its flow properties are not described by a linear relationship between shear stress (\(\tau\)) and shear rate (\(\dot{gamma}\)). This dependency can manifest as shear-thinning (viscosity decreases with stress) or shear-thickening (viscosity increases with stress).
Non-Newtonian Fluid Definition
The fundamental difference between Newtonian and non-Newtonian fluids lies in their response to shear. For a Newtonian fluid, the relationship is linear, defined by Newton’s law of viscosity: \(\tau = \mu \dot{gamma}\), where \(\mu\) is the constant coefficient of viscosity. For non-Newtonian fluids, this relationship is non-linear and can be time-dependent. The apparent viscosity, defined as \(\eta = \tau / \dot{gamma}\), is not a constant but a function of the shear rate itself, \(\eta(\dot{gamma})\).
This behavior arises from the fluid’s internal microstructure, such as long polymer chains, suspended particles, or emulsions. When a shear force is applied, these microstructures can align, deform, or rearrange, altering the fluid’s resistance to flow. For example, in a polymer solution (a shear-thinning fluid), the randomly coiled polymer chains untangle and align with the flow direction under high shear, reducing internal friction and thus viscosity. Conversely, in a concentrated suspension like cornstarch in water (a shear-thickening fluid), the particles may jam together under high shear, drastically increasing viscosity.
The study of these complex flow behaviors is called rheology. Understanding a fluid’s non-Newtonian properties is critical in many industrial processes, from pumping and mixing to coating and molding, as the processing conditions directly influence the material’s behavior.
Type
Disruption
Usage
Precursors
- Isaac Newton’s law of viscosity (1687)
- Studies on colloids and suspensions by Thomas Graham (1860s)
- Development of viscometry techniques
- Early observations of anomalous flow in materials like clay slurries and paints
Applications
- food processing (e.g., ketchup, mayonnaise)
- cosmetics (e.g., creams, nail polish)
- drilling muds in the oil industry
- liquid body armor
- paint manufacturing
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