» Lithium-ion Intercalation Mechanism

Lithium-ion Intercalation Mechanism

1980
  • M. Stanley Whittingham
  • John B. Goodenough
  • Akira Yoshino

Lithium-ion batteries function via an intercalation mechanism, a reversible insertion of ions into a layered host material. During discharge, ions ([latex]Li^+[/latex]) de-intercalate from a negative electrode (anode), typically graphite, and move through a non-aqueous electrolyte to intercalate into a positive electrode (cathode), typically a metal oxide. Electrons travel through the external circuit, creating current.

The concept of intercalation is central to the success of lithium-ion batteries. Unlike older battery chemistries where the electrodes undergo significant chemical phase changes, intercalation involves lithium ions acting as ‘guests’ that slide into and out of the ‘host’ crystalline structure of the electrode materials. For the anode, the host is typically graphite, which has a layered structure allowing [latex]Li^+[/latex] ions to fit between its graphene sheets, forming [latex]LiC_6[/latex]. For the cathode, the host is a metal oxide, such as lithium cobalt oxide ([latex]LiCoO_2[/latex]), where lithium ions occupy layers between cobalt oxide sheets.

This process is highly reversible and does not dramatically alter the host’s structure, which leads to a long cycle life with minimal degradation. The movement of ions is facilitated by a non-aqueous organic electrolyte, as lithium is highly reactive with water. A micro-porous polymer separator keeps the anode and cathode from touching and short-circuiting while allowing ions to pass through.

During charging, an external voltage forces the process to reverse: lithium ions are extracted from the cathode, travel back across the electrolyte, and re-insert into the graphite anode. The high electrochemical potential of lithium, combined with its low atomic weight, allows for batteries with very high energy density and specific energy, which is why they have revolutionized portable electronics and are enabling the transition to electric vehicles.

UNESCO Nomenclature: 2203
– Electrochemistry

类型

Chemical Process

Disruption

Revolutionary

使用方法

Widespread Use

Precursors

  • Discovery of lithium metal and its high electrochemical potential
  • Fundamental research on intercalation compounds in the 1970s
  • Development of stable non-aqueous electrolytes
  • Early, unsafe prototypes of rechargeable lithium metal batteries

应用

  • smartphones, laptops, and tablets
  • electric vehicles (EVs)
  • cordless power tools and garden equipment
  • grid-scale energy storage systems
  • implantable medical devices and hearing aids

专利:

  • US4357215A

Potential Innovations Ideas

级别需要会员

您必须是!!等级!!会员才能访问此内容。

立即加入

已经是会员? 在此登录
Related to: lithium-ion, intercalation, anode, cathode, electrolyte, rechargeable, energy density, graphite

发表回复

您的邮箱地址不会被公开。 必填项已用 * 标注

迎接新挑战
机械工程师、项目或研发经理
有效的产品开发

可在短时间内接受新的挑战。
通过 LinkedIn 联系我
塑料金属电子集成、成本设计、GMP、人体工程学、中高容量设备和耗材、受监管行业、CE 和 FDA、CAD、Solidworks、精益西格玛黑带、医疗 ISO 13485

我们正在寻找新的赞助商

 

您的公司或机构从事技术、科学或研究吗?
> 给我们发送消息 <

接收所有新文章
免费,无垃圾邮件,电子邮件不分发也不转售

或者您可以免费获得完整会员资格以访问所有受限制的内容>这里<

Historical Context

(if date is unknown or not relevant, e.g. "fluid mechanics", a rounded estimation of its notable emergence is provided)

Related Invention, Innovation & Technical Principles

滚动至顶部

你可能还喜欢