Shear-thickening, or dilatancy, is a non-Newtonian behavior where viscosity increases with the rate of shear stress. A classic example is a suspension of cornstarch in water (oobleck), which feels liquid when stirred slowly but becomes almost solid when struck or stirred rapidly. This phenomenon is caused by the jamming of suspended particles under high shear.
Shear-Thickening (Dilatancy)
- Osborne Reynolds
The mechanism behind shear-thickening in concentrated suspensions is often attributed to hydroclustering and jamming. At low shear rates, the suspended particles are lubricated by the surrounding liquid and can move past each other relatively easily. As the shear rate increases, the particles are forced closer together. The lubricating layer of fluid between them thins, and strong, short-range hydrodynamic forces cause the particles to form transient clusters, or ‘hydroclusters’.
At a critical shear rate, these hydroclusters can percolate across the system, forming a rigid, stress-bearing network that spans the fluid. This transition from a flowing state to a jammed, solid-like state is what causes the dramatic increase in viscosity. This process is reversible; when the high shear stress is removed, the particle network breaks apart, and the material returns to its fluid state. This property is exploited in technologies like liquid body armor, where a flexible material containing a shear-thickening fluid instantly becomes rigid upon the high-speed impact of a projectile, dissipating the energy and protecting the wearer.
Type
Disruption
Utilisation
Precursors
- Observations of the behavior of wet sand by Osborne Reynolds
- Studies of concentrated colloidal suspensions
- Development of rheometers to study high-shear phenomena
Applications
- liquid body armor (e.g., d3o) that hardens on impact
- traction control systems where fluid thickens to lock a differential
- pot-hole filling materials that flow into cracks but harden under traffic pressure
- protective gear for sports
- seismic dampers for buildings
Brevets :
- US7226878B2
- US7381467B2
Potential Innovations Ideas
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