Oxy-acetylene welding uses a flame produced by the combustion of acetylene (\(C_2H_2\)) with pure oxygen. The reaction occurs in two stages. The primary reaction in the inner, white-hot cone is incomplete, producing carbon monoxide and hydrogen: \(2C_2H_2 + 2O_2 \rightarrow 4CO + 2H_2\). These hot gases then react with atmospheric oxygen in the outer envelope, completing the combustion.
The two-stage combustion process is key to the effectiveness of oxy-acetylene welding. The primary reaction, \(2C_2H_2 + 2O_2 \rightarrow 4CO + 2H_2\), is highly exothermic and is concentrated in the small inner cone of the flame, which reaches temperatures of approximately 3,500 °C (6,330 °F), making it the hottest-burning common fuel gas. This intense, localized heat is ideal for creating a molten weld pool quickly and efficiently.
The secondary reaction occurs in the larger, bluish outer flame envelope, where the products of the first reaction (carbon monoxide and hydrogen) are burned using oxygen from the surrounding air: \(4CO + 2H_2 + 3O_2 \rightarrow 4CO_2 + 2H_2O\). This secondary combustion releases additional heat, but over a much larger area, serving to preheat the metal ahead of the weld and protect the molten weld pool from atmospheric oxygen and nitrogen. This protective shield of burnt gases prevents oxidation and embrittlement of the weld metal, which is crucial for creating a strong, ductile joint. The balance between the two stages is controlled by the oxygen-to-acetylene ratio set at the torch, allowing for different flame characteristics (neutral, carburizing, or oxidizing) suitable for various metals and applications.
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