Galvanic Corrosion

Bernoulli's principle states that for an inviscid flow, an increase in a fluid's speed occurs simultaneously with a decrease in pressure or a decrease in its potential energy. It is a statement of the conservation of energy for a moving fluid, commonly expressed as [latex]p + \frac{1}{2}\rho v^2 + \rho gh = \text{constant}[/latex] along a streamline.

In continuum mechanics, the principle of mass conservation states that the mass of a closed system must remain constant over time. For a fluid, this is expressed by the continuity equation. In its Eulerian differential form, it is written as [latex]\frac{\partial \rho}{\partial t} + \nabla \cdot (\rho \mathbf{u}) = 0[/latex], where [latex]\rho[/latex] is the density and [latex]\mathbf{u}[/latex] is the velocity field.

A reformulation of classical mechanics based on the principle of stationary action. It uses a scalar quantity called the Lagrangian, defined as kinetic energy minus potential energy ([latex]L = T - V[/latex]). The equations of motion are derived from the Euler-Lagrange equation, [latex]\frac{d}{dt} \left( \frac{\partial L}{\partial \dot{q}_i} \right) - \frac{\partial L}{\partial q_i} = 0[/latex], using generalized coordinates, which simplifies analysis of complex systems with constraints.

The Cauchy stress tensor, denoted [latex]\boldsymbol{\sigma}[/latex], is a second-order tensor that completely defines the state of stress at a point inside a material. It relates the traction vector (force per unit area) [latex]\mathbf{T}[/latex] on any surface passing through that point to the surface's normal vector [latex]\mathbf{n}[/latex] via the linear relationship [latex]\mathbf{T} = \boldsymbol{\sigma} \cdot \mathbf{n}[/latex].

A reformulation of classical mechanics that uses generalized coordinates and their conjugate momenta. It is based on the Hamiltonian function, [latex]H(q, p, t)[/latex], representing the system's total energy. The dynamics are described by Hamilton's equations: [latex]\dot{q}_i = \frac{\partial H}{\partial p_i}[/latex] and [latex]\dot{p}_i = -\frac{\partial H}{\partial q_i}[/latex]. This framework is central to quantum mechanics and statistical mechanics.

For a Newtonian fluid, viscosity is a function of temperature and pressure but not shear rate. In liquids, viscosity decreases significantly as temperature increases because higher thermal energy allows molecules to overcome cohesive intermolecular forces more easily. Conversely, in gases, viscosity increases with temperature as more frequent molecular collisions at higher speeds lead to greater momentum transfer.

A Newtonian fluid's shear stress is directly proportional to the rate of shear strain. This linear relationship is defined by Newton's law of viscosity: [latex]\tau = \mu \frac{du}{dy}[/latex], where [latex]\tau[/latex] is the shear stress, [latex]\mu[/latex] is the dynamic viscosity (a constant of proportionality), and [latex]\frac{du}{dy}[/latex] is the shear rate or velocity gradient.

Fluid mechanics is the branch of applied mechanics concerned with the statics (fluids at rest) and dynamics (fluids in motion) of liquids and gases. It applies fundamental principles of mass, momentum, and energy conservation to analyze and predict fluid behavior. Its applications are vast, ranging from aerodynamics and hydraulics to meteorology and oceanography.

These are two ways to describe motion in continuum mechanics:

• the Lagrangian specification follows individual material particles, tracking their properties over time, like watching a specific car in traffic
• the Eulerian specification focuses on fixed points in space, observing the properties (velocity, density) of whatever particles pass through those points, like a traffic camera observing a fixed intersection.

Solid mechanics is a branch of continuum mechanics that studies the behavior of solid materials, especially their motion and deformation under the action of forces, temperature changes, or other external loads. It is fundamental to engineering for the design and analysis of structures. Key areas include elasticity (recoverable deformation), plasticity (permanent deformation), and fracture mechanics (crack initiation and propagation).

The Navier–Stokes equations are a set of non-linear partial differential equations describing the motion of viscous fluid substances. They are a statement of Newton's second law, balancing momentum changes with pressure gradients, viscous forces, and external forces. For an incompressible fluid, the equation is [latex]\rho (\frac{\partial \mathbf{v}}{\partial t} + \mathbf{v} \cdot \nabla \mathbf{v}) = -\nabla p + \mu \nabla^2 \mathbf{v} + \mathbf{f}[/latex].

Cathodic protection (CP) is a technique used to control the corrosion of a metal surface by making it the cathode of an electrochemical cell. This is achieved by supplying an external electrical current that suppresses the natural corrosion currents. The protected metal's potential is polarized to a more negative value, shifting it into a region of immunity or passivity.

A fundamental principle stating that the total energy of an isolated system remains constant over time. Energy can neither be created nor destroyed, only transformed from one form to another, such as from potential to kinetic energy. In classical mechanics, for systems with only conservative forces, the total mechanical energy [latex]E = T + V[/latex] is conserved.

Viscoelasticity is the property of materials that exhibit both viscous and elastic characteristics when undergoing deformation. Viscous materials, like honey, resist shear flow and strain linearly with time when a stress is applied. Elastic materials, like a rubber band, strain when stretched and quickly return to their original state once the stress is removed. Viscoelastic materials have elements of both.