Cathodic Protection

The electric current in a Voltaic pile is produced by a redox reaction. At the zinc anode, zinc metal is oxidized, releasing two electrons per atom ([latex]Zn \rightarrow Zn^{2+} + 2e^{-}[/latex]). These electrons travel through the external circuit to the copper cathode. There, hydrogen ions from the aqueous electrolyte are reduced, forming hydrogen gas ([latex]2H^{+} + 2e^{-} \rightarrow H_2[/latex]).

A primary flaw of the Voltaic pile is electrode polarization. During operation, hydrogen gas produced at the copper cathode forms an insulating layer of bubbles on its surface. This layer increases the battery's internal resistance and reduces the surface area available for reaction. As a result, the voltage and current output of the pile drop significantly shortly after it begins to be used.

The Navier–Stokes equations are a set of non-linear partial differential equations describing the motion of viscous fluid substances. They are a statement of Newton's second law, balancing momentum changes with pressure gradients, viscous forces, and external forces. For an incompressible fluid, the equation is [latex]\rho (\frac{\partial \mathbf{v}}{\partial t} + \mathbf{v} \cdot \nabla \mathbf{v}) = -\nabla p + \mu \nabla^2 \mathbf{v} + \mathbf{f}[/latex].

This law states that the electromotive force (EMF, [latex]\mathcal{E}[/latex]) induced in any closed circuit is equal to the negative of the time rate of change of the magnetic flux ([latex]\Phi_B[/latex]) through the circuit. The mathematical expression is [latex]\mathcal{E} = -\frac{d\Phi_B}{dt}[/latex]. This principle is the basis for electric generators, transformers, and inductors, describing the macroscopic effect of induction.

Lenz's law provides the direction of the induced electromotive force (EMF) and current resulting from electromagnetic induction. It states that the induced current will flow in a direction that creates a magnetic field opposing the change in magnetic flux that produced it. This principle is a consequence of the conservation of energy and is represented by the negative sign in Faraday's law.

A fundamental principle stating that the total energy of an isolated system remains constant over time. Energy can neither be created nor destroyed, only transformed from one form to another, such as from potential to kinetic energy. In classical mechanics, for systems with only conservative forces, the total mechanical energy [latex]E = T + V[/latex] is conserved.

The first electric battery, it produces a direct current by stacking pairs of dissimilar metal discs (e.g., zinc and copper) separated by brine-soaked cloth. Each pair forms a galvanic cell, and stacking them in series increases the overall voltage. This arrangement demonstrated the first continuous conversion of chemical energy into electrical energy, paving the way for modern electrochemistry.

The Voltaic pile established the principle of adding voltages by connecting electrochemical cells in series. Each zinc-copper pair, or cell, generates a characteristic electromotive force (EMF) of approximately 0.76 volts. By physically stacking these cells, Volta demonstrated that the total voltage across the pile is the sum of the individual EMFs of each cell, as described by [latex]V_{total} = n \times V_{cell}[/latex].

The continuum assumption treats fluids as continuous matter rather than as discrete molecules. This simplification is valid when the length scale of the problem is much larger than the intermolecular distance, allowing properties like density and velocity to be defined at infinitesimally small points. This enables the use of differential equations to describe the macroscopic behavior of fluid flow.

The Cauchy stress tensor, denoted [latex]\boldsymbol{\sigma}[/latex], is a second-order tensor that completely defines the state of stress at a point inside a material. It relates the traction vector (force per unit area) [latex]\mathbf{T}[/latex] on any surface passing through that point to the surface's normal vector [latex]\mathbf{n}[/latex] via the linear relationship [latex]\mathbf{T} = \boldsymbol{\sigma} \cdot \mathbf{n}[/latex].

A primary source of electromotive force is electromagnetic induction, described by Faraday's law. It states that a time-varying magnetic flux [latex]\Phi_B[/latex] through a circuit loop induces an EMF ([latex]\mathcal{E}[/latex]). The magnitude of the EMF is proportional to the rate of change of the flux, given by the equation [latex]\mathcal{E} = - \frac{d\Phi_B}{dt}[/latex]. This principle is the foundation for electric generators, transformers, and inductors.

A reformulation of classical mechanics that uses generalized coordinates and their conjugate momenta. It is based on the Hamiltonian function, [latex]H(q, p, t)[/latex], representing the system's total energy. The dynamics are described by Hamilton's equations: [latex]\dot{q}_i = \frac{\partial H}{\partial p_i}[/latex] and [latex]\dot{p}_i = -\frac{\partial H}{\partial q_i}[/latex]. This framework is central to quantum mechanics and statistical mechanics.

An improvement on the Voltaic pile, the Daniell cell consists of a copper electrode in a copper(II) sulfate solution and a zinc electrode in a zinc sulfate solution, separated by a porous barrier. This two-fluid design prevents hydrogen gas buildup (polarization) on the copper electrode, resulting in a much more stable and reliable voltage source for a longer duration.

Viscoelasticity is the property of materials that exhibit both viscous and elastic characteristics when undergoing deformation. Viscous materials, like honey, resist shear flow and strain linearly with time when a stress is applied. Elastic materials, like a rubber band, strain when stretched and quickly return to their original state once the stress is removed. Viscoelastic materials have elements of both.