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The Claude Process for Liquefaction

1902
  • Georges Claude
Gas liquefaction plant utilizing the Claude process for industrial applications.

The Claude process improves upon the Hampson-Linde cycle by incorporating an expansion engine or turbine. A portion of the compressed gas does work in an expander, causing a much larger temperature drop (nearly isentropic expansion) than Joule-Thomson expansion alone. This provides more efficient cooling, making it the dominant method for large-scale gas liquefaction and separation today.

Georges Claude recognized the thermodynamic inefficiency of relying solely on the isenthalpic Joule-Thomson effect. He reasoned that making the gas perform external work during expansion would extract more energy and thus produce a greater cooling effect. In his system, the main stream of high-pressure gas is split. One part goes to an expansion engine, where it cools significantly while producing work. This extremely cold gas is then used to pre-cool the other part of the high-pressure stream in a heat exchanger. This second stream then undergoes a final Joule-Thomson expansion to produce the liquid. By combining the bulk cooling from the expander with the final-stage liquefaction from the J-T valve, the Claude cycle achieves higher efficiency and can operate at lower initial pressures than the Linde cycle. The work produced by the expander can also be recovered to help power the initial compressor, further improving overall efficiency. This principle is fundamental to virtually all modern large-scale cryogenic plants.

UNESCO Nomenclature: 2212
– Thermodynamics

Type

Thermodynamic Cycle

Disruption

Incremental

Usage

Widespread Use

Precursors

  • Hampson-Linde Cycle
  • Brayton cycle (thermodynamic basis for the expansion engine)
  • Joule-Thomson effect
  • Development of reliable high-speed expansion engines and turbines

Applications

  • large-scale industrial air separation units (ASUs)
  • production of liquid nitrogen, oxygen, and argon
  • helium and hydrogen liquefaction plants
  • liquefied natural gas (LNG) production
  • turboexpanders in natural gas processing

Patents:

  • FR324949A

Potential Innovations Ideas

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Related to: Claude process, expansion engine, liquefaction, cryogenics, air separation, Georges Claude, isentropic expansion, thermodynamics, efficiency, LNG.

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Historical Context

(if date is unknown or not relevant, e.g. "fluid mechanics", a rounded estimation of its notable emergence is provided)

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