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Publicações recentes – Patentes de baterias de íon-sódio

Baterias de íons de sódio

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Sodium-ion batteries
A tecnologia de baterias de íon-sódio oferece uma alternativa promissora para íon de lítio Sistemas com materiais exclusivos para cátodo e ânodo, priorizando custo, estabilidade e desempenho em aplicações de armazenamento de energia.

As baterias de íon-sódio são células de armazenamento de energia eletroquímica que substituem os íons de sódio pelos metais. lítio como as espécies transportadoras de carga que transitam entre o cátodo e o ânodo durante os ciclos de carga e descarga, operando em uma química de inserção e extração mecanicamente análoga à do íon lítio, mas regida pelo maior raio iônico do sódio, menor potencial de redução e abundância crustal substancialmente maior.

A tecnologia de materiais catódicos divide-se em três famílias principais:

  • óxidos de metais de transição em camadas
  • Análogos do azul da Prússia
  • Compostos polianiônicos, incluindo fosfatos e sulfatos do tipo NASICON.

Cada uma apresentando diferentes vantagens e desvantagens em termos de capacidade específica, patamar de tensão, estabilidade estrutural sob sodiação repetida e custo de síntese; nenhuma química de cátodo isoladamente alcançou a consolidação de mercado que NMC e LFP detêm no setor de íon-lítio.

No lado do ânodo, a capacidade de intercalação de sódio insignificante do grafite o torna inadequado, direcionando a pesquisa para carbono duro derivado de biomassa ou precursores de resina como o padrão prático atual, com ânodos de sódio metálico representando uma fronteira de maior energia, porém propensa à formação de dendritos. A formulação do eletrólito — sais de NaPF6 ou NaClO4 em solventes de éter ou carbonato, líquidos iônicos ou condutores de sódio de estado sólido emergentes — determina criticamente a química da interface do eletrólito sólido que governa a eficiência coulombiana do primeiro ciclo, a capacidade de taxa e o envelhecimento por tempo.

 

 As publicações e patentes indexadas abaixo abordam a síntese de materiais de cátodo e ânodo, engenharia de eletrólitos, caracterização da SEI (interface eletrólito-eletrodo), projeto de formato de célula, otimização do protocolo de formação e modelagem tecnoeconômica em nível de sistema.

Esta é a nossa mais recente seleção de publicações e patentes mundiais em inglês sobre baterias de íon-sódio, provenientes de diversos periódicos científicos online, classificadas e focadas em bateria de íon-sódio, célula de íon-sódio, cátodo de íon-sódio, cátodo de óxido de sódio em camadas, cátodo análogo ao azul da Prússia, cátodo polianiônico de sódio, cátodo NASICON, ânodo de sódio de carbono duro, ânodo de sódio de carbono macio, ânodo de sódio metálico, eletrólito de íon-sódio, eletrólito de sódio à base de éter, eletrólito de sal de sódio, eletrólito NaPF6, íon-sódio, eletrólito sólido e camada SEI de íon-sódio.

Method for manufacturing anode active material layer and method for manufacturing secondary battery

Patent published on the 2026-06-11 in US under Ref US20260162953 by TOYOTA JIDOSHA KK [JP] (Imano Manabu [jp])

Abstract: A method for manufacturing an anode active material layer includes: a step of preparing an anode slurry by mixing an anode active material, a solid electrolyte, a conductive additive, a binder, and a solvent; a step of obtaining a parameter of the anode slurry using a dynamic viscoelasticity measuring device; a step of determining quality of a coating film based on the obtained parameter; and a step of applying the anode slurry that has been determined to be acceptable in the step of determining[...]


Our summary: The method involves preparing an anode slurry with specific components. It uses a dynamic viscoelasticity measuring device to obtain parameters of the slurry. The quality of the coating film is determined before applying the acceptable anode slurry.

anode active material, secondary battery, dynamic viscoelasticity, coating film quality

Patent

Negative electrode for all-solid-state sodium ion secondary battery, method for manufacturing same, and all-solid-state sodium ion secondary battery

Patent published on the 2026-06-11 in WO under Ref WO2026121155 by NIPPON ELECTRIC GLASS CO LTD [JP] (Tatsuoka Deguchi Mina [jp], Tsunoda Kei [jp], Demizu Masashi [jp], Yamauchi Hideo [jp])

Abstract: Provided are: a negative electrode for an all-solid-state sodium ion secondary battery, the negative electrode being capable of improving the initial charge/discharge efficiency, the conservation characteristics, the output characteristics, and the cycle characteristics of the all-solid-state sodium ion secondary battery; a method for manufacturing the negative electrode; and an all-solid-state sodium ion secondary battery. The negative electrode for an all-solid-state sodium ion secondary batte[...]


Our summary: This content describes a negative electrode designed for all-solid-state sodium ion secondary batteries. It highlights improvements in charge/discharge efficiency and cycle characteristics. Additionally, it outlines a manufacturing method for the negative electrode.

negative electrode, all-solid-state battery, sodium ion, manufacturing method

Patent

Solid electrolyte, method for producing same, and power storage device

Patent published on the 2026-06-11 in WO under Ref WO2026121260 by TOAGOSEI CO LTD [JP] (Hiraoka Hideki [jp], Goto Takeshi [jp])

Abstract: This solid electrolyte includes: a film-like porous body having communication holes; and molecular crystals containing, as structural units, an alkali metal salt and organic molecules having at least one type of atom selected from the group consisting of sulfur atoms, oxygen atoms, nitrogen atoms, and phosphorus atoms. The molecular crystals are retained in the communication holes.[...]


Our summary: The solid electrolyte features a porous film-like body with communication holes. It incorporates molecular crystals made from alkali metal salts and organic molecules containing specific atoms. These molecular crystals are securely held within the communication holes.

solid electrolyte, power storage device, alkali metal salt, molecular crystals

Patent

Method for manufacturing cathode active material layer and method for manufacturing secondary battery

Patent published on the 2026-06-11 in US under Ref US20260160658 by TOYOTA JIDOSHA KK [JP] (Imano Manabu [jp])

Abstract: [0000] A method for manufacturing a cathode active material layer includes: a step of preparing a cathode slurry by mixing a cathode active material, a solid electrolyte, a conductive additive, a binder, and a solvent; a step of obtaining a parameter of the cathode slurry using a dynamic viscoelasticity measuring device; a step of determining the quality of a coating film based on the parameter; and a step of applying the cathode slurry that has been determined to be acceptable in the step of de[...]


Our summary: The method involves preparing a cathode slurry with specific components. It measures the slurry s parameters using dynamic viscoelasticity. The quality of the coating film is determined before applying the acceptable slurry.

cathode active material, secondary battery, dynamic viscoelasticity, coating film quality

Patent

Solid electrolyte separator and all-solid-state battery comprising same

Patent published on the 2026-06-04 in WO under Ref WO2026116626 by SAMSUNG SDI CO LTD [KR] (Son Inhyuk [kr], Jo Sungnim [kr], Shim Kyueun [kr], Yun Jonghyuk [kr], Lim Hyungsub [kr], Park Taehyun [kr], Lee Jieun [kr])

Abstract: Provided are a solid electrolyte separator and an all-solid-state battery comprising same, the solid electrolyte separator: comprising a solid electrolyte and an ion-conductive polymer; and having an embossed portion formed on at least one surface thereof.[...]


Our summary: The content describes a solid electrolyte separator used in all-solid-state batteries. This separator consists of a solid electrolyte combined with an ion-conductive polymer. It features an embossed portion on at least one of its surfaces.

solid electrolyte, all-solid-state battery, ion-conductive polymer, embossed separator

Patent

All-solid-state battery

Patent published on the 2026-06-04 in WO under Ref WO2026116617 by SAMSUNG ELECTRO MECH CO LTD [KR] (Kim Junhyeon [kr], Jung Jihyung [kr], Lee Tae Gyeom [kr], Kim Nahyeon [kr], Kim Han [kr], Kim Doyeon [kr])

Abstract: Provided are an all-solid-state battery and a method of manufacturing the same. The all-solid-state battery includes a positive electrode layer, a negative electrode layer, and a solid electrolyte layer between the positive electrode layer and the negative electrode layer The solid electrolyte layer includes a first material and a second material The first material includes at least one selected from a lithium chloroboracite (LCBA)-based compound and a lithium borosilicate (LBSO)-based compound,[...]


Our summary: The all-solid-state battery consists of a positive electrode, a negative electrode, and a solid electrolyte layer. The solid electrolyte layer is made from a combination of lithium-based compounds and selected metals. A method for manufacturing this battery is also provided.

all-solid-state battery, solid electrolyte, lithium compounds, manufacturing method

Patent

Crosslinked Zwitterionic PVA-g-SBMA/PEDOT:PSS Networks for Mechanically Robust All-Solid-State Electrolytes

Published on 2026-01-28 by Chia-Wen Wei, Chia-Yu Chen, Shyh-Chyang Luo, Dmitry G. Belov, Szu-Nan Yang @MDPI

Abstract: Conventional lithium-ion batteries face issues like electrolyte leakage and interface instability. Solid-state lithium batteries with solid electrolytes address these, while solid-state polymer electrolytes (SPEs) offer safety and flexibility. This study primarily aimed to develop and synthesize a graft copolymer, PVA-g-SBMA, which was successfully synthesized by grafting [2-(methacryloyloxy)ethyl] dimethyl-(3-sulfopropyl)ammonium hydroxide (SBMA) onto poly(vinyl alcohol) (PVA). PVA provided exc[...]


Our summary: This study developed a graft copolymer, PVA-g-SBMA, by grafting SBMA onto PVA to enhance ionic conductivity and mechanical properties in solid-state electrolytes. The copolymer was crosslinked with PEDOT:PSS to form a robust network, improving film performance. The optimal system achieved a conductivity of 4.9 × 10⁻⁴ S/cm at room temperature with specific lithium salt concentrations.

Crosslinked, Zwitterionic, Solid-state, Electrolytes

Publication

Advances in Sodium Ion Batteries Based on Mixed Electrolytes of ILs and Organic Solvents

Published on 2026-01-28 by Sajjad Ghiyami, Claudio Mele @MDPI

Abstract: Sodium-ion batteries (SIBs) represent a topic of extreme interest in the research field, especially because the materials used are cheaper than those in lithium-ion batteries (LIBs). In SIBs, the choice of cathodes and electrolytes is very important because they will affect the energy density, cycling stability, and safety of the battery. This work focuses on the prospect of hybrid electrolyte cells that incorporate ionic liquids (ILs) into organic liquids in order to improve the safety and perf[...]


Our summary: This study explores the use of hybrid electrolytes combining ionic liquids and organic solvents in sodium-ion batteries. It highlights improvements in ionic conductivity, electrochemical stability, and thermal safety. The research suggests that these advancements could enhance the performance and lifecycle of sodium-ion battery technology for large-scale energy storage applications.

Sodium-ion batteries, hybrid electrolytes, ionic liquids, energy storage

Publication

Tópicos abordados: Baterias de íon-sódio, armazenamento eletroquímico de energia, materiais catódicos, materiais anódicos, óxidos de metais de transição em camadas, análogos do azul da Prússia, compostos polianiônicos, intercalação de sódio, interface de eletrólito sólido, eficiência coulombiana, formulação de eletrólitos, modelagem técnico-econômica, ISO 18604, IEC 62619, IEC 62133, ASTM D7862 e ISO 9001.

Glossário de termos utilizados

Network-attached storage (NAS): Um dispositivo de armazenamento conectado a uma rede que permite o acesso e o compartilhamento de dados entre múltiplos usuários e dispositivos, geralmente oferecendo armazenamento centralizado de arquivos, backup e recursos de gerenciamento. Ele opera independentemente de um computador e pode ser acessado por meio de protocolos de rede padrão.

Contexto histórico

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