
나트륨 이온 배터리는 나트륨 이온을 다른 이온으로 대체하여 에너지를 저장하는 전기화학 전지입니다. 리튬 나트륨은 충전 및 방전 주기 동안 음극과 양극 사이를 오가는 전하 운반체로서, 리튬 이온과 유사한 메커니즘으로 삽입 및 추출 화학 반응을 통해 작동하지만, 나트륨의 더 큰 이온 반경, 더 낮은 환원 전위, 그리고 훨씬 더 풍부한 지각 매장량에 의해 좌우됩니다.
음극 소재 기술은 크게 세 가지 주요 계열로 나뉩니다.
- 층상 전이 금속 산화물
- 프러시안 블루 유사품
- NASICON형 인산염 및 황산염을 포함하는 다음이온 화합물
각각은 특정 용량, 전압 평탄도, 반복적인 나트륨화에 따른 구조적 안정성 및 합성 비용 측면에서 뚜렷한 장단점을 나타내며, 어떤 단일 양극 화학 물질도 리튬 이온 시장에서 NMC와 LFP가 차지하는 것과 같은 시장 점유율을 확보하지 못했습니다.
양극 측면에서 흑연은 나트륨 삽입 능력이 매우 미미하여 부적합하며, 현재 실용적인 표준으로 바이오매스 또는 수지 전구체에서 유래한 경질 탄소에 대한 연구가 진행되고 있습니다. 나트륨 금속 양극은 더 높은 에너지를 제공하지만 덴드라이트 생성이 용이한 새로운 연구 분야입니다. 전해질 조성(에테르 또는 탄산염 용매에 용해된 NaPF6 또는 NaClO4 염, 이온성 액체, 또는 새롭게 개발되고 있는 고체 나트륨 전도체)은 초기 사이클 쿨롱 효율, 속도 성능 및 시간 경과에 따른 노화를 좌우하는 고체 전해질 계면 화학을 결정하는 데 매우 중요합니다.
아래에 색인된 논문 및 특허는 음극 및 양극 재료 합성, 전해질 엔지니어링, SEI 특성 분석, 셀 형식 설계, 형성 프로토콜 최적화 및 시스템 수준의 기술 경제성 모델링을 다룹니다.
본 자료는 전 세계 과학 온라인 저널에 게재된 나트륨 이온 배터리 관련 영문 논문 및 특허를 엄선하여 정리한 최신 자료입니다. 나트륨 이온 배터리, Na-이온 셀, 나트륨 이온 음극, 층상 산화물 음극 나트륨, 프러시안 블루 유사 음극, 폴리아니온 음극 나트륨, NASICON 음극, 경질 탄소 양극 나트륨, 연질 탄소 양극 나트륨, 나트륨 금속 양극, 나트륨 이온 전해질, 에테르계 전해질 나트륨, 나트륨염 전해질, NaPF6 전해질, 나트륨 이온, 고체 전해질, 나트륨 이온 SEI 층 등의 키워드를 중심으로 분류 및 정리했습니다.
Method for manufacturing anode active material layer and method for manufacturing secondary battery
Patent published on the 2026-06-11 in US under Ref US20260162953 by TOYOTA JIDOSHA KK [JP] (Imano Manabu [jp])
Abstract: A method for manufacturing an anode active material layer includes: a step of preparing an anode slurry by mixing an anode active material, a solid electrolyte, a conductive additive, a binder, and a solvent; a step of obtaining a parameter of the anode slurry using a dynamic viscoelasticity measuring device; a step of determining quality of a coating film based on the obtained parameter; and a step of applying the anode slurry that has been determined to be acceptable in the step of determining[...]
Our summary: The method involves preparing an anode slurry with specific components. It uses a dynamic viscoelasticity measuring device to obtain parameters of the slurry. The quality of the coating film is determined before applying the acceptable anode slurry.
anode active material, secondary battery, dynamic viscoelasticity, coating film quality
Patent
Negative electrode for all-solid-state sodium ion secondary battery, method for manufacturing same, and all-solid-state sodium ion secondary battery
Patent published on the 2026-06-11 in WO under Ref WO2026121155 by NIPPON ELECTRIC GLASS CO LTD [JP] (Tatsuoka Deguchi Mina [jp], Tsunoda Kei [jp], Demizu Masashi [jp], Yamauchi Hideo [jp])
Abstract: Provided are: a negative electrode for an all-solid-state sodium ion secondary battery, the negative electrode being capable of improving the initial charge/discharge efficiency, the conservation characteristics, the output characteristics, and the cycle characteristics of the all-solid-state sodium ion secondary battery; a method for manufacturing the negative electrode; and an all-solid-state sodium ion secondary battery. The negative electrode for an all-solid-state sodium ion secondary batte[...]
Our summary: This content describes a negative electrode designed for all-solid-state sodium ion secondary batteries. It highlights improvements in charge/discharge efficiency and cycle characteristics. Additionally, it outlines a manufacturing method for the negative electrode.
negative electrode, all-solid-state battery, sodium ion, manufacturing method
Patent
Solid electrolyte, method for producing same, and power storage device
Patent published on the 2026-06-11 in WO under Ref WO2026121260 by TOAGOSEI CO LTD [JP] (Hiraoka Hideki [jp], Goto Takeshi [jp])
Abstract: This solid electrolyte includes: a film-like porous body having communication holes; and molecular crystals containing, as structural units, an alkali metal salt and organic molecules having at least one type of atom selected from the group consisting of sulfur atoms, oxygen atoms, nitrogen atoms, and phosphorus atoms. The molecular crystals are retained in the communication holes.[...]
Our summary: The solid electrolyte features a porous film-like body with communication holes. It incorporates molecular crystals made from alkali metal salts and organic molecules containing specific atoms. These molecular crystals are securely held within the communication holes.
solid electrolyte, power storage device, alkali metal salt, molecular crystals
Patent
Method for manufacturing cathode active material layer and method for manufacturing secondary battery
Patent published on the 2026-06-11 in US under Ref US20260160658 by TOYOTA JIDOSHA KK [JP] (Imano Manabu [jp])
Abstract: [0000] A method for manufacturing a cathode active material layer includes: a step of preparing a cathode slurry by mixing a cathode active material, a solid electrolyte, a conductive additive, a binder, and a solvent; a step of obtaining a parameter of the cathode slurry using a dynamic viscoelasticity measuring device; a step of determining the quality of a coating film based on the parameter; and a step of applying the cathode slurry that has been determined to be acceptable in the step of de[...]
Our summary: The method involves preparing a cathode slurry with specific components. It measures the slurry s parameters using dynamic viscoelasticity. The quality of the coating film is determined before applying the acceptable slurry.
cathode active material, secondary battery, dynamic viscoelasticity, coating film quality
Patent
Solid electrolyte separator and all-solid-state battery comprising same
Patent published on the 2026-06-04 in WO under Ref WO2026116626 by SAMSUNG SDI CO LTD [KR] (Son Inhyuk [kr], Jo Sungnim [kr], Shim Kyueun [kr], Yun Jonghyuk [kr], Lim Hyungsub [kr], Park Taehyun [kr], Lee Jieun [kr])
Abstract: Provided are a solid electrolyte separator and an all-solid-state battery comprising same, the solid electrolyte separator: comprising a solid electrolyte and an ion-conductive polymer; and having an embossed portion formed on at least one surface thereof.[...]
Our summary: The content describes a solid electrolyte separator used in all-solid-state batteries. This separator consists of a solid electrolyte combined with an ion-conductive polymer. It features an embossed portion on at least one of its surfaces.
solid electrolyte, all-solid-state battery, ion-conductive polymer, embossed separator
Patent
All-solid-state battery
Patent published on the 2026-06-04 in WO under Ref WO2026116617 by SAMSUNG ELECTRO MECH CO LTD [KR] (Kim Junhyeon [kr], Jung Jihyung [kr], Lee Tae Gyeom [kr], Kim Nahyeon [kr], Kim Han [kr], Kim Doyeon [kr])
Abstract: Provided are an all-solid-state battery and a method of manufacturing the same. The all-solid-state battery includes a positive electrode layer, a negative electrode layer, and a solid electrolyte layer between the positive electrode layer and the negative electrode layer The solid electrolyte layer includes a first material and a second material The first material includes at least one selected from a lithium chloroboracite (LCBA)-based compound and a lithium borosilicate (LBSO)-based compound,[...]
Our summary: The all-solid-state battery consists of a positive electrode, a negative electrode, and a solid electrolyte layer. The solid electrolyte layer is made from a combination of lithium-based compounds and selected metals. A method for manufacturing this battery is also provided.
all-solid-state battery, solid electrolyte, lithium compounds, manufacturing method
Patent
Crosslinked Zwitterionic PVA-g-SBMA/PEDOT:PSS Networks for Mechanically Robust All-Solid-State Electrolytes
Published on 2026-01-28 by Chia-Wen Wei, Chia-Yu Chen, Shyh-Chyang Luo, Dmitry G. Belov, Szu-Nan Yang @MDPI
Abstract: Conventional lithium-ion batteries face issues like electrolyte leakage and interface instability. Solid-state lithium batteries with solid electrolytes address these, while solid-state polymer electrolytes (SPEs) offer safety and flexibility. This study primarily aimed to develop and synthesize a graft copolymer, PVA-g-SBMA, which was successfully synthesized by grafting [2-(methacryloyloxy)ethyl] dimethyl-(3-sulfopropyl)ammonium hydroxide (SBMA) onto poly(vinyl alcohol) (PVA). PVA provided exc[...]
Our summary: This study developed a graft copolymer, PVA-g-SBMA, by grafting SBMA onto PVA to enhance ionic conductivity and mechanical properties in solid-state electrolytes. The copolymer was crosslinked with PEDOT:PSS to form a robust network, improving film performance. The optimal system achieved a conductivity of 4.9 × 10⁻⁴ S/cm at room temperature with specific lithium salt concentrations.
Crosslinked, Zwitterionic, Solid-state, Electrolytes
Publication
Advances in Sodium Ion Batteries Based on Mixed Electrolytes of ILs and Organic Solvents
Published on 2026-01-28 by Sajjad Ghiyami, Claudio Mele @MDPI
Abstract: Sodium-ion batteries (SIBs) represent a topic of extreme interest in the research field, especially because the materials used are cheaper than those in lithium-ion batteries (LIBs). In SIBs, the choice of cathodes and electrolytes is very important because they will affect the energy density, cycling stability, and safety of the battery. This work focuses on the prospect of hybrid electrolyte cells that incorporate ionic liquids (ILs) into organic liquids in order to improve the safety and perf[...]
Our summary: This study explores the use of hybrid electrolytes combining ionic liquids and organic solvents in sodium-ion batteries. It highlights improvements in ionic conductivity, electrochemical stability, and thermal safety. The research suggests that these advancements could enhance the performance and lifecycle of sodium-ion battery technology for large-scale energy storage applications.
Sodium-ion batteries, hybrid electrolytes, ionic liquids, energy storage
Publication











