This is a fundamental equation in quantum mechanics that describes how the quantum state of a physical system changes over time. It is a linear partial differential equation for the wavefunction, [latex]\Psi(x, t)[/latex]. The time-dependent version is [latex]i\hbar\frac{\partial}{\partial t}\Psi = \hat{H}\Psi[/latex], where [latex]\hat{H}[/latex] is the Hamiltonian operator, representing the total energy of the system.
Schrödinger Equation
- Erwin Schrödinger
The Schrödinger equation is the quantum mechanical counterpart to Newton’s second law in classical mécanique. While Newton’s law predicts the trajectory of a particle, the Schrödinger equation predicts the future behavior of a system’s wavefunction. The wavefunction, [latex]\Psi[/latex], is a complex-valued probability amplitude, and the square of its magnitude, [latex]|\Psi|^2[/latex], gives the probability density of finding the particle at a given position and time. The equation comes in two main forms: time-dependent and time-independent.
The time-dependent Schrödinger equation (TDSE), [latex]i\hbar\frac{\partial}{\partial t}\Psi(x, t) = \hat{H}\Psi(x, t)[/latex], describes a system evolving in time. The time-independent Schrödinger equation (TISE), [latex]\hat{H}\Psi(x) = E\Psi(x)[/latex], is used for systems in a stationary state, where the energy [latex]E[/latex] is constant. Solving the TISE for a given potential yields the allowed energy eigenvalues ([latex]E[/latex]) and the corresponding energy eigenfunctions ([latex]\Psi[/latex]), which represent the stable states of the system, such as the electron orbitals in an atom. The Hamiltonian operator [latex]\hat{H}[/latex] is constructed from the classical expression for the total energy (kinetic plus potential) by replacing classical variables with their corresponding quantum operators. For a single non-relativistic particle, [latex]\hat{H} = -\frac{\hbar^2}{2m}\nabla^2 + V(x, t)[/latex].
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Disruption
Utilisation
Precursors
- Hamiltonian mechanics (1833)
- De Broglie’s wave-particle duality hypothesis (1924)
- Matrix mechanics (Heisenberg, 1925)
- Classical wave equations
Applications
- predicting atomic and molecular orbitals (quantum chemistry)
- designing semiconductor devices
- modeling nuclear reactions
- understanding superconductivity
- quantum computing algorithm design
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