Maison » In-Situ Chemical Oxidation (ISCO)

In-Situ Chemical Oxidation (ISCO)

1990
Field technician performing in-situ chemical oxidation for environmental remediation of pollutants.

In-Situ Chemical Oxidation (ISCO) is an aggressive remediation technology that involves injecting strong chemical oxidants directly into the contaminated subsurface to destroy pollutants. Common oxidants include permanganate, persulfate, hydrogen peroxide (Fenton’s reagent), and ozone. These chemicals react with contaminants, converting them into less toxic substances like carbon dioxide, water, and inorganic salts, without requiring excavation of the contaminated material.

ISCO is a powerful méthode for rapidly degrading a wide range of organic contaminants in both soil and groundwater. The selection of the oxidant is crucial and depends on the target contaminant, geochemistry of the site, and safety considerations. Potassium permanganate ([latex]KMnO_4[/latex]) is effective against chlorinated ethenes like PCE and TCE but is less effective for petroleum hydrocarbons. Fenton’s reagent, a mixture of hydrogen peroxide ([latex]H_2O_2[/latex]) and an iron catalyst, generates highly reactive hydroxyl radicals ([latex]\bullet OH[/latex]) that can non-selectively destroy most organic compounds. Persulfate ([latex]S_2O_8^{2-}[/latex]), activated by heat, high pH, or iron, is more stable than Fenton’s reagent and can travel further in the subsurface. Ozone ([latex]O_3[/latex]) is a gas that is typically sparged into the subsurface to treat both saturated and unsaturated zones.

A major challenge in ISCO is achieving effective delivery and distribution of the oxidant to the target contamination zone. The subsurface is often heterogeneous, and the oxidant can be consumed by non-target reactions with natural organic matter or minerals in the soil, a phenomenon known as natural oxidant demand (NOD). This can significantly increase the amount of chemical required. Furthermore, ISCO reactions can be highly exothermic, potentially causing hazardous conditions, and can mobilize toxic metals like chromium by changing the redox conditions of the aquifer. Despite these challenges, ISCO is often chosen for its speed in reducing high contaminant concentrations in source areas.

UNESCO Nomenclature: 2506
– Environmental sciences

Type

Chemical Process

Disruption

Substantial

Utilisation

Widespread Use

Precursors

  • understanding of redox chemistry and reaction kinetics
  • industrial use of chemical oxidants in wastewater treatment
  • advances in drilling and injection technologies for subsurface access
  • development of analytical chemistry methods to monitor contaminant degradation

Applications

  • treatment of dense non-aqueous phase liquids (dnapls) like TCE
  • remediation of petroleum hydrocarbon plumes
  • destruction of pesticides and herbicides in soil and groundwater
  • cleanup of sites contaminated with polycyclic aromatic hydrocarbons (pahs)
  • rapid source zone treatment to reduce contaminant mass

Brevets :

QUE

Potential Innovations Ideas

!niveaux !!! Adhésion obligatoire

Vous devez être membre de l'association pour accéder à ce contenu.

S’inscrire maintenant

Vous êtes déjà membre ? Connectez-vous ici
Related to: ISCO, in-situ chemical oxidation, remediation, groundwater, soil, Fenton’s reagent, permanganate, persulfate, contaminant destruction, oxidant.

Laisser un commentaire

Votre adresse e-mail ne sera pas publiée. Les champs obligatoires sont indiqués avec *

DISPONIBLE POUR DE NOUVEAUX DÉFIS
Mechanical Engineer, Project, Process Engineering or R&D Manager
Développement de produits efficace

Disponible pour un nouveau défi dans un court délai.
Contactez-moi sur LinkedIn
Plastic metal electronics integration, Design-to-cost, GMP, Ergonomics, Medium to high-volume devices & consumables, Lean Manufacturing, Regulated industries, CE & FDA, CAD, Solidworks, Lean Sigma Black Belt, medical ISO 13485

Nous recherchons un nouveau sponsor

 

Votre entreprise ou institution est dans le domaine de la technique, de la science ou de la recherche ?
> envoyez-nous un message <

Recevez tous les nouveaux articles
Gratuit, pas de spam, email non distribué ni revendu

ou vous pouvez obtenir votre adhésion complète - gratuitement - pour accéder à tout le contenu restreint >ici<

Historical Context

(if date is unknown or not relevant, e.g. "fluid mechanics", a rounded estimation of its notable emergence is provided)

Related Invention, Innovation & Technical Principles

Retour en haut

Vous aimerez peut-être aussi