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Últimas publicaciones y patentes sobre estructuras orgánicas covalentes (COF)

Estructuras orgánicas covalentes

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Esta es nuestra última selección de publicaciones y patentes mundiales en inglés sobre Covalent Organic Frameworks (COFs), entre muchas revistas científicas online, clasificadas y centradas en marco orgánico covalente, química covalente dinámica (DCC), síntesis ionotérmica, síntesis reticular, unidad de construcción secundaria, enlace β-Ketoenamina, síntesis solvotérmica, síntesis de interfase, síntesis interfacial, síntesis mecanoquímica, condensación de iminas y química covalente dinámica.

Single-crystal metal-free helical covalent polymers

Patent published on the 2026-05-07 in US under Ref US20260125559 by UNIV CITY HONG KONG [HK] (Zhang Qichun [hk], Xue Miaomiao [hk])

Abstract: This invention relates to the development of covalent organic frameworks (COFs) and/or covalent organic polymers (COPs) utilizing tellurium-based dynamic covalent bonds (—Te—O—B— and —Te—O—P—) to create high-quality single crystals with unique properties. This invention also provides concise and efficient methods to grow large single crystals of tellurium-based polymers, overcoming challenges associated with misassembly and poor crystallinity during synthesis. The tellurium-based[...]


Our summary: This invention focuses on developing covalent organic frameworks and polymers using tellurium-based dynamic covalent bonds. It presents methods for growing large single crystals while addressing synthesis challenges. The resulting materials show enhanced stability, suitable for various applications.

Covalent organic frameworks, Tellurium-based polymers, Single-crystal synthesis, Dynamic covalent bonds

Patent

Slips surface coatings

Patent published on the 2026-04-16 in WO under Ref WO2026078041 by UCL BUSINESS LTD [GB] (Tiwari Manish K [gb], Zhang Jianhui [gb], Mandal Priya [gb], Singh Vikaramjeet [gb])

Abstract: The present disclosure relates to surface coatings comprising a reticulated structure that is a metal-organic framework having pores or a covalent organic framework having pores, and a lubricant comprising lubricant molecules, wherein the lubricant molecules are held within the pores of the reticulated structure and extend from the pore apertures thereof. Also disclosed are methods of making such coatings, surfaces comprising such coatings, and kits comprising the reticulated structure and the l[...]


Our summary: The disclosure details surface coatings with a reticulated structure that incorporates lubricant molecules within its pores. It describes methods for creating these coatings and surfaces that utilize them. Additionally, it includes kits containing the reticulated structure and lubricant.

surface coatings, metal-organic framework, lubricant molecules, reticulated structure

Patent

Layered covalent organic framework having new structure

Patent published on the 2026-01-22 in WO under Ref WO2026018930 by INST OF SCIENCE TOKYO [JP] (Murakami Yoichi [jp], Kitano Tomoki [jp], Goto Syunto [jp])

Abstract: Provided is a COF characterized by the following items to. Building block molecules used to generate the COF include a tetra-building block molecule having a functional group at the position of each vertex of a tetrahedron and a tri-building block molecule having a functional group at the position of each vertex of a triangle. The functional group of the tetra-building block molecule and the functional group of the tri-building block molecule can form a covalent bond by condensation reaction the[...]


Our summary: A new layered covalent organic framework (COF) is described. It is constructed from tetra- and tri-building block molecules that form covalent bonds through condensation reactions. The COF can be partially dissolved to produce a film from the resulting solution or dispersion.

Covalent Organic Framework, Tetra-building Block, Tri-building Block, Layered Structure

Patent

Metal&ndash;Support Interactions in Single-Atom Catalysts for Electrochemical CO2 Reduction

Published on 2026-01-13 by Alexandra Mansilla-Roux, Mayra Anabel Lara-Angulo, Juan Carlos Serrano-Ruiz @MDPI

Abstract: Electrochemical CO2 reduction (CO2RR) is a promising route to transform a major greenhouse gas into value-added fuels and chemicals. However, its deployment is still hindered by the sluggish activation of CO2, poor selectivity toward multielectron products, and competition with the hydrogen evolution reaction (HER). Single-atom catalysts (SACs) have emerged as powerful materials to address these challenges because they combine maximal metal utilization with well-defined coordination environments[...]


Our summary: This minireview discusses the role of single-atom catalysts (SACs) in enhancing electrochemical CO2 reduction efficiency. It highlights how metal-support interactions influence the adsorption and conversion of CO2RR intermediates. The review also addresses design strategies and future directions for improving SAC performance in industrial applications.

Single-atom catalysts, electrochemical CO2 reduction, metal-support interactions, selectivity descriptors

Publication

Controlled One-Step Synthesis of Monodisperse CeO2 Octahedra in a Binary Solvent System with Waste Liquid Recycling

Published on 2025-12-30 by Yaohui Xu, Yu Hu, Nengwei Zeng, Haimei Wang, Yuan Zhang, Zongjie Liu, Xinrui Chen, Zhao Ding @MDPI

Abstract: To overcome the limitations of template-dependent and anion-assisted methods, this work presents a solvent-controlled strategy for the one-step solvothermal synthesis of octahedral CeO2. Using only Ce(NO3)3&amp;middot;6H2O in methanol/water (MeOH/H2O) mixtures without the addition of auxiliary templates or surfactants, phase-pure cubic CeO2 was obtained. Well-defined octahedra were exclusively formed in a 15 mL MeOH/5 mL H2O system at 180 &amp;deg;C for 12 h, whereas other alcohols (incl[...]


Our summary: This study presents a one-step solvothermal method for synthesizing monodisperse CeO2 octahedra using a methanol/water solvent system. The process avoids templates and surfactants, yielding phase-pure cubic CeO2 with defined morphology. Additionally, the solvothermal mother liquor can be recycled multiple times, enhancing sustainability.

CeO2 synthesis, monodisperse octahedra, solvent-controlled strategy, waste liquid recycling

Publication

Mechanochemically Synthesized Nanocrystalline Cu2ZnSnSe4 as a Multifunctional Material for Energy Conversion and Storage Applications

Published on 2025-12-12 by Angel Agnes Johnrose, Devika Rajan Sajitha, Vengatesh Panneerselvam, Anandhi Sivaramalingam, Kamalan Kirubaharan Amirtharaj Mosas, Beauno Stephen, Shyju Thankaraj Salammal @MDPI

Abstract: Cu2ZnSnSe4 is a promising light-absorbing material for cost-effective and eco-friendly thin-film solar cells; however, its synthesis often leads to secondary phases that limit device efficiency. To overcome these challenges, we devised a straightforward and efficient method to obtain single-phase Cu2ZnSnSe4 nanocrystalline powders directly from the elements Cu, Zn, Sn, and Se via mechanochemical synthesis followed by vacuum annealing at 450 &amp;deg;C. Phase evolution monitored by X-ray diff[...]


Our summary: Mechanochemically synthesized Cu2ZnSnSe4 demonstrates potential for thin-film solar cells and energy storage. The method yields phase-pure nanocrystalline powders with optimal crystallite sizes and confirmed stoichiometry. Electrical and optical analyses indicate promising characteristics for photovoltaic applications and energy density.

Nanocrystalline, Cu2ZnSnSe4, mechanochemical synthesis, energy conversion

Publication

Green Mechanochemical Synthesis of Binary and Ternary Cadmium Chalcogenides with Tunable Band Gaps

Published on 2025-11-15 by Matja Kristl, Nea Zanjkovi?, Jona Kunej, Sao Gyergyek, Janja Stergar @MDPI

Abstract: In this work, we report on the mechanochemical preparation and characterization of binary (CdS, CdSe, and CdTe) and ternary (CdS0.5Se0.5, CdS0.5Te0.5, and CdSe0.5Te0.5) cadmium chalcogenides. The compounds were synthesized in a planetary micro mill using a zirconia grinding bowl and zirconia grinding balls. The products were examined by powder X-ray diffraction (pXRD), transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDX), dynamic light scattering (DLS), UV&amp;n[...]


Our summary: This study presents the mechanochemical synthesis of binary and ternary cadmium chalcogenides. Characterization techniques confirm the formation of nanoparticles with tunable band gaps suitable for semiconducting applications. The method is environmentally friendly, avoiding solvents and toxic precursors.

Mechanochemical synthesis, Cadmium chalcogenides, Tunable band gaps, Green chemistry

Publication

Temas tratados: Elementos de Tierras Raras, Recubrimiento de Barrera Térmica, Microestructura, Propiedades Mecánicas, Síntesis por Combustión en Solución, Dureza Vickers, Tenacidad a la Fractura, Expansión Térmica, Efecto Hall, Dopado, Perovskita, Resistencia a la Corrosión, Ensayo de Ciclo Térmico, Refinamiento del Grano, Rendimiento a Alta Temperatura, Densidad de Portadores de Carga, Propiedades de Transporte, Organización Internacional de Normalización (ISO), ASTM Internacional, Instituto Nacional Americano de Normalización (ANSI), Comisión Electrotécnica Internacional (IEC) y Organización Internacional de Normalización (ISO).

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