Chemical Electromotive Force

Electromotive force (EMF) and electric potential difference (voltage) are distinct concepts, though both are measured in volts. EMF is the work per unit charge done by a non-conservative force (e.g., chemical reaction, changing magnetic field) to move charge within a source. Potential difference is the work per unit charge done by the conservative electrostatic field between two points.

The Reynolds number ([latex]\text{Re}[/latex]) is a dimensionless quantity in fluid mechanics used to predict flow patterns by representing the ratio of inertial forces to viscous forces. Low Reynolds numbers characterize smooth, orderly laminar flow, while high Reynolds numbers indicate chaotic, eddy-filled turbulent flow. It is crucial for determining the dynamic behavior of a fluid and for scaling experiments.

The Mach number (M) is a dimensionless quantity representing the ratio of flow velocity past a boundary to the local speed of sound: [latex]M = v/a[/latex], where v is the flow velocity and a is the speed of sound. It is the primary indicator of compressibility effects. As Mach number approaches and exceeds 1, the density of the air changes significantly, altering aerodynamic forces.

The Reynolds-Averaged Navier-Stokes (RANS) equations are time-averaged equations of motion for turbulent fluid flow. This approach, called Reynolds decomposition, separates flow variables into a mean and a fluctuating component. The averaging process introduces an additional term, the Reynolds stress tensor, which represents the effect of turbulence and must be modeled to achieve closure, making simulations computationally tractable.

The absolute electrochemical potential of a single electrode cannot be measured. Instead, potentials are measured relative to a universally accepted reference. The Standard Hydrogen Electrode (SHE) is the primary reference, assigned a potential of exactly 0 volts under standard conditions (1 M [latex]H^+[/latex] concentration, 1 bar [latex]H_2[/latex] gas, 298 K). All other standard electrode potentials are reported relative to this zero point.

The Kutta-Joukowski theorem quantifies the lift force generated by an airfoil. It states that the lift per unit span ([latex]L'[/latex]) is directly proportional to the fluid density ([latex]\rho[/latex]), the free-stream velocity ([latex]V[/latex]), and the circulation ([latex]\Gamma[/latex]) around the body: [latex]L' = \rho V \Gamma[/latex]. This links the abstract concept of circulation to the physical force of lift.

The Boltzmann distribution describes the probability that a system in thermal equilibrium at temperature T will be in a specific microstate with energy E. This probability is proportional to the Boltzmann factor, [latex]e^{-E / k_B T}[/latex]. It implies that states with lower energy are exponentially more likely to be occupied than states with higher energy, with temperature modulating this preference.

This foundational formula connects the macroscopic thermodynamic quantity of entropy (S) with the number of possible microscopic arrangements, or microstates (W), corresponding to the system's macroscopic state. The equation, [latex]S = k_B \ln W[/latex], reveals that entropy is a measure of statistical disorder or randomness. The constant [latex]k_B[/latex] is the Boltzmann constant, linking energy at the particle level with temperature.

Shear-thickening, or dilatancy, is a non-Newtonian behavior where viscosity increases with the rate of shear stress. A classic example is a suspension of cornstarch in water (oobleck), which feels liquid when stirred slowly but becomes almost solid when struck or stirred rapidly. This phenomenon is caused by the jamming of suspended particles under high shear.

The Nernst equation relates the reduction potential of a half-cell (or the total voltage of an electrochemical cell) to the standard electrode potential, temperature, and the activities (often approximated by concentrations) of the chemical species undergoing redox. The equation is [latex]E = E^{\circ} - \frac{RT}{nF} \ln Q[/latex], where Q is the reaction quotient.

Motional EMF is generated when a conductor moves through a magnetic field. The magnetic component of the Lorentz force, [latex]\mathbf{F} = q(\mathbf{v} \times \mathbf{B})[/latex], acts on the charge carriers within the conductor, causing them to move and create a charge separation. This separation establishes an electric field and a potential difference. The resulting EMF is given by the line integral [latex]\mathcal{E} = \oint (\mathbf{v} \times \mathbf{B}) \cdot d\mathbf{l}[/latex].

In a system at thermodynamic equilibrium, the electrochemical potential, [latex]\bar{\mu}_i[/latex], for any given charged species `i` must be uniform throughout all phases. If a gradient exists ([latex]\nabla \bar{\mu}_i \neq 0[/latex]), ions will spontaneously move from regions of higher potential to lower potential, creating a current or flux, until this gradient is eliminated and equilibrium is re-established.

Energy is not continuous but comes in discrete packets called quanta. The energy [latex]E[/latex] of a single quantum of electromagnetic radiation (a photon) is directly proportional to its frequency [latex]\nu[/latex]. This relationship is defined by the Planck-Einstein relation, [latex]E = h\nu[/latex], where [latex]h[/latex] is the Planck constant. This concept fundamentally challenged classical physics.

A statistical ensemble is a conceptual tool consisting of a large number of virtual copies of a system, each representing a possible microstate. By averaging properties over all systems in the ensemble, one can calculate macroscopic observables. The main types are the microcanonical (isolated system with fixed N, V, E), canonical (closed system, fixed N, V, T), and grand canonical (open system, fixed µ, V, T).